Self-Organization of Porphyrin-POM Dyads: Nonplanar Diacids and Oxoanions in Low-Dimensional H-Bonding Networks

Article Multidisciplinary Sciences

Shape-assisted self-assembly

Joseph F. Woods et al.

Summary: This article discusses the importance of self-assembly and molecular recognition in the creation of complexity, and emphasizes the role of topography in supramolecular constructs.

NATURE COMMUNICATIONS (2022)

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Article Chemistry, Multidisciplinary

Elucidating Atropisomerism in Nonplanar Porphyrins with Tunable Supramolecular Complexes

Karolis Norvaisa et al.

Summary: This study sheds light on the fundamental issue of atropisomerism in porphyrins, using benzenesulfonic acid for host-guest interactions and NMR spectroscopy to characterize all four rotamers. The research suggests that charge-assisted complexation is key to unraveling the atropisomeric enigma in porphyrinoids. Additionally, X-ray structural analysis was used to investigate weak host-guest interactions in nonplanar porphyrins.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Review Chemistry, Inorganic & Nuclear

A historical perspective on porphyrin-based metal-organic frameworks and their applications

Xuan Zhang et al.

Summary: Porphyrins are important molecules widely found in nature, and recent interest in using them as building blocks for metal-organic frameworks has increased rapidly. Porphyrin-based MOFs with atomically precise structures provide an ideal platform for studying structure-function relationships in the solid state without compromising the inherent properties of the porphyrin building blocks.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Organic

An Insight into Non-Covalent Interactions on the Bicyclo[1.1.1]pentane Scaffold

Nitika Grover et al.

Summary: Bicyclo[1.1.1]pentane (BCP) is extensively studied as a bioisosteric component of drugs. Analysis of BCP derivatives revealed various non-covalent interactions, such as halogen bonding and N-H center dot center dot center dot O contacts, which can be useful for designing BCP analogs of drugs. Computational analysis and structure determinations provide insights into the interaction profiles of BCP derivatives with specific active sites.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2021)

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Review Chemistry, Inorganic & Nuclear

The shape of porphyrins

Christopher J. Kingsbury et al.

Summary: The article discusses the impact of porphyrin molecule shape and conformation on substitution patterns, proposing a quantitative method based on the Normal-coordinate Structural Decomposition approach for predictive evaluation of porphyrin structures.

COORDINATION CHEMISTRY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Decisive Influence of Environment on Aromatic/Aromatic Interaction Geometries. Comparison of Aromatic/Aromatic Interactions in Crystal Structures of Small Molecules and in Protein Structures

Jelena M. Zivkovic et al.

Summary: The study found that the geometries of aromatic/aromatic interactions are more influenced by crystal packing/surrounding than by substituents. While interactions in crystal structures from the CSD prefer parallel stacking interactions at large offsets, those in proteins from the PDB prefer T-shaped geometries with small offsets.

CRYSTAL GROWTH & DESIGN (2021)

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Article Biochemistry & Molecular Biology

2D Porphyrinic Metal-Organic Frameworks Featuring Rod-Shaped Secondary Building Units

Rory Elliott et al.

Summary: Metal-organic frameworks (MOFs) are a rapidly expanding class of materials with diverse potential applications, with 'rod MOFs' representing an underexplored subclass. In this study, two new 2D porphyrinic rod MOFs, PROD-1 and PROD-2, were prepared using a Cu-II complex, showcasing promising structural attributes for future photocatalytic investigations.

MOLECULES (2021)

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Review Chemistry, Multidisciplinary

Porphyrins and Polyoxometalate Scaffolds

Raphael Lamare et al.

Summary: This review discusses the combination of porphyrins and polyoxometalates, highlighting the challenges faced in optimizing hybrid materials for applications.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

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Article Chemistry, Multidisciplinary

Surface-confined formation of conjugated porphyrin-based nanostructures on Ag(111)

Nan Cao et al.

Summary: Porphyrin-based oligomers were synthesized on surfaces by forming C=C linkages through the condensation of absorbed 4-benzaldehyde-substituted porphyrins following a McMurry-type coupling scheme. The dissociation of aldehyde groups and the formation of C=C linkages were evidenced by scanning tunneling microscopy, non-contact atomic force microscopy, and X-ray photoelectron spectroscopy data. This approach offers a pathway for creating functional conjugated nanostructures using porphyrin-based oligomers coupled by C=C bridges.

NANOSCALE (2021)

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Review Chemistry, Multidisciplinary

Classic highlights in porphyrin and porphyrinoid total synthesis and biosynthesis

Mathias O. Senge et al.

Summary: Porphyrins play crucial roles in nature and modern applications, with their photochemical properties determining the biochemical functions of plants. Through complexation with metals, they can be utilized in various contemporary applications such as solar energy generation.

CHEMICAL SOCIETY REVIEWS (2021)

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Article Chemistry, Multidisciplinary

Long-Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin-Calixarene Assemblies

Massimiliano Gaeta et al.

CHEMISTRY-A EUROPEAN JOURNAL (2020)

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Article Biochemistry & Molecular Biology

Weak Interactions and Conformational Changes in Core-Protonated A2- and Ax-Type Porphyrin Dications

Christopher J. Kingsbury et al.

MOLECULES (2020)

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Crystal structure and photophysical properties of a novel polyoxomolybdate porphyrin

Wen-Tong Chen

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2020)

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Structure determination and negative differential resistance of tetraarylporphyrin/polyoxometalate 2: 1 complexes

Yoshito Yamazaki et al.

JOURNAL OF MATERIALS CHEMISTRY C (2020)

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Review Chemistry, Multidisciplinary

Molecular Engineering of Free-Base Porphyrins as Ligands-The N-H•••X Binding Motif in Tetrapyrroles

Marc Kielmann et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Conformational Re-engineering of Porphyrins as Receptors with Switchable N-H•••X-Type Binding Modes

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ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2019)

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Article Chemistry, Organic

Incremental Introduction of Organocatalytic Activity into Conformationally Engineered Porphyrins

Marc Kielmann et al.

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY (2019)

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Article Chemistry, Multidisciplinary

Efficient photocatalytic proton- coupled electrontransfer reduction of O2 using a saddle- distorted porphyrin as a photocatalyst

Emi Aoki et al.

CHEMICAL COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Conformational control of nonplanar free base porphyrins: towards bifunctional catalysts of tunable basicity

M. Roucan et al.

CHEMICAL COMMUNICATIONS (2018)

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A supramolecular photocatalyst composed of a polyoxometalate and a photosensitizing water-soluble porphyrin diacid for the oxidation of organic substrates in water

Tomoya Ishizuka et al.

GREEN CHEMISTRY (2018)

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Article Chemistry, Multidisciplinary

Porphyrin stacks as an efficient molecular glue to induce chirality in hetero-component calixarene-porphyrin assemblies

Alessandro D'Urso et al.

NEW JOURNAL OF CHEMISTRY (2017)

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Article Chemistry, Multidisciplinary

Interactions of a water-soluble calix[4]arene with spermine: solution and solid-state characterisation

Alessandro D'Urso et al.

SUPRAMOLECULAR CHEMISTRY (2016)

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Article Multidisciplinary Sciences

A switchable self-assembling and disassembling chiral system based on a porphyrin-substituted phenylalanine-phenylalanine motif

Georgios Charalambidis et al.

NATURE COMMUNICATIONS (2016)

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The Cambridge Structural Database

Colin R. Groom et al.

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS (2016)

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SHELXT - Integrated space-group and crystal-structure determination

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES (2015)

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PLATON SQUEEZE: a tool for the calculation of the disordered solvent contribution to the calculated structure factors

Anthony L. Spek

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

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Crystal structure refinement with SHELXL

George M. Sheldrick

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY (2015)

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Serial time-resolved crystallography of photosystem II using a femtosecond X-ray laser

Christopher Kupitz et al.

NATURE (2014)

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New supramolecular compounds based on porphyrin and polyoxometalate: synthesis, characterization and nonlinear optical and optical limiting properties

Zonghai Shi et al.

RSC ADVANCES (2014)

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Review Multidisciplinary Sciences

Supramolecular Chirality in Porphyrin Chemistry

Victor Borovkov

SYMMETRY-BASEL (2014)

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Localized interaction of single porphyrin molecules with oxygen vacancies on TiO2(110)

Markus Lackinger et al.

JOURNAL OF CHEMICAL PHYSICS (2012)

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ShelXle: a Qt graphical user interface for SHELXL

Christian B. Huebschle et al.

JOURNAL OF APPLIED CRYSTALLOGRAPHY (2011)

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Porphyrin-layered double hydroxide/polymer composites as novel ecological photoactive surfaces

Eva Kafunkova et al.

JOURNAL OF MATERIALS CHEMISTRY (2010)

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Review Chemistry, Multidisciplinary

Self-Organized Porphyrinic Materials

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CHEMICAL REVIEWS (2009)

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Supramolecular Chemistry of Metalloporphyrins

Irina Beletskaya et al.

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Nanoporous Crystals of Calixarene/Porphyrin Supramolecular Complex Functionalized by Diffusion and Coordination of Metal Ions

Rita De Zorzi et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2009)

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A discrete supramolecular conglomerate composed of two saddle-distorted zinc(II)-phthalocyanine complexes and a doubly protonated porphyrin with saddle distortion undergoing efficient photoinduced electron transfer

Takahiko Kojima et al.

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Crystal engineering of nanoporous architectures and chiral porphyrin assemblies

Israel Goldberg

CRYSTENGCOMM (2008)

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Exercises in molecular gymnastics - bending, stretching and twisting porphyrins

MO Senge

CHEMICAL COMMUNICATIONS (2006)

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Synthesis and structure of 16 π octaalkyltetraphenylporphyrins

Y Yamamoto et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2005)

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Rationalization of supramolecular chirality in a bisporphyrin system

VV Borovkov et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2004)

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Self-assembly to ordered films of the homoassociate solutions of the tetrasodium salt of 5,10,15,20-tetrakis(4-sulfonatophenyl) porphyrin dihydrochloride

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The Protein Data Bank

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NUCLEIC ACIDS RESEARCH (2000)

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Self-Organization of Porphyrin-POM Dyads: Nonplanar Diacids and Oxoanions in Low-Dimensional H-Bonding Networks

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