期刊
MOLECULES
卷 27, 期 20, 页码 -出版社
MDPI
DOI: 10.3390/molecules27207083
关键词
cyclophane; conformation; supramolecule; 3D molecule; NHC carbene; review
This paper reviews the most stable conformation of crystalline three-dimensional cyclophane achieved by self-assembling based on changing the type of aromatic compound or regulating the type and number of bridging groups. The study found that [3(n)] cyclophanes have stronger donor capability and could potentially serve as a new type of electron donor for innovative electron conductive materials.
This paper reviews the most stable conformation of crystalline three-dimensional cyclophane (CP) achieved by self-assembling based on changing the type of aromatic compound or regulating the type and number of bridging groups. [3(n)]cyclophanes (CPs) were reported to form supramolecular compounds with bind organic, inorganic anions, or neutral molecules selectively. [3(n)]cyclophanes ([3(n)]CPs) have stronger donor capability relative to compound [2(n)]cyclophanes ([2(n)]CPs), and it is expected to be a new type of electron donor for the progress of fresh electron conductive materials. The synthesis, conformational behavior, and properties of crystalline multi-bridge rings are summarized and discussed.
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