4.6 Article

Design of Pd-Zn Bimetal MOF Nanosheets and MOF-Derived Pd3.9Zn6.1/CNS Catalyst for Selective Hydrogenation of Acetylene under Simulated Front-End Conditions

期刊

MOLECULES
卷 27, 期 17, 页码 -

出版社

MDPI
DOI: 10.3390/molecules27175736

关键词

metal-organic framework; porphyrin; nanosheet; palladium-zinc intermetallic; carbonization; selective hydrogenation; acetylene

资金

  1. American Chemical Society Petroleum Research Fund
  2. ACS PRF [57596-UR5]
  3. Welch Foundation [T-0014]
  4. Key R&D and Promotion Special Project (Science and Technology) of Henan Province, China [212102210214]

向作者/读者索取更多资源

Novel zinc-palladium-porphyrin bimetal metal-organic framework (MOF) nanosheets were synthesized and transformed into carbon-supported Pd-Zn intermetallics with different Pd: Zn atomic ratios. Pd3.9Zn6.1 showed the best catalytic performance for selective hydrogenation.
Novel zinc-palladium-porphyrin bimetal metal-organic framework (MOF) nanosheets were directly synthesized by coordination chelation between Zn(II) and Pd(II) tetra(4-carboxyphenyl) porphin (TCPP(Pd)) using a solvothermal method. Furthermore, a serial of carbon nanosheets supported Pd-Zn intermetallics (Pd-Zn-ins/CNS) with different Pd: Zn atomic ratios were obtained by one-step carbonization under different temperature using the prepared Zn-TCPP(Pd) MOF nanosheets as precursor. In the carbonization process, Pd-Zn-ins went through the transformation from PdZn (650 degrees C) to Pd3.9Zn6.1 (similar to 950 degrees C) then to Pd3.9Zn6.1/Pd (1000 degrees C) with the temperature increasing. The synthesized Pd-Zn-ins/CNS were further employed as catalysts for selective hydrogenation of acetylene. Pd3.9Zn6.1 showed the best catalytic performance compared with other Pd-Zn intermetallic forms.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.6
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据