期刊
MINERALS ENGINEERING
卷 189, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.mineng.2022.107890
关键词
Oxidized pyrrhotite; Mixed collector; Flotation; Benzohydroxamic acid; Sodium butyl xanthate
资金
- National Nature Science of China [51874221]
- Open of Hubei Key Laboratory of Mineral Resources Processing and Environment [ZHJJ202004]
- Open Foundation of State Key Laboratory of Mineral Processing [BGRIMM-KJSKL-2020-24]
This study used a mixture of benzohydroxamic acid (BHA) and sodium butyl xanthate (SBX) as a collector for the flotation of moderately oxidized pyrrhotite (MOP) and found that it significantly improved the flotation recovery. The measurement results showed that the mixed collector had a stronger interaction with the MOP surface, improving its floatability. Fourier transform infrared spectroscopy (FTIR) analysis revealed that the interaction between BHA and MOP reduced the hydrophilic substance on the mineral surface, allowing other collectors to adsorb more easily onto the fresh unoxidized surface.
The benzohydroxamic acid (BHA) and sodium butyl xanthate (SBX) mixture was used as a collector for the flotation of moderately oxidized pyrrhotite (MOP) in this work. Microflotation results revealed that the flotation recovery of MOP was not very high with the addition of individual SBX or BHA collector, but significantly improved using a mixed collector of SBA/BHA, the maximum flotation recovery of could reach 88.55%. Zeta potential measurement revealed that the surface charges of MOP were negatively moved after the addition of mixed SBX/BHA compared to adding SBX or BHA alone, revealing a much stronger interaction between the collector mixture and MOP surface, leading to the improvement of MOP floatability. The FTIR spectra analysis revealed that the synergistic effect of SBX/BHA was attributed to the interaction between BHA and MOP, which could reduce the hydrophilic Fe(OH)(3) on the pyrrhotite surface, allowing more adsorption of SBX onto the generated fresh unoxidized surfaces.
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