4.2 Article

Tracking nitrogen-to-nickel ratio and prevalent paramagnetic species in synthetic diamonds by electron spin resonance at 90 K

期刊

MENDELEEV COMMUNICATIONS
卷 32, 期 5, 页码 645-648

出版社

ELSEVIER
DOI: 10.1016/j.mencom.2022.09.026

关键词

synthetic diamond; impurities; high pressure and high temperature; electron spin resonance; solid state chemistry; analytical chemistry

资金

  1. Ioffe Institute [0040-2014-0013]
  2. JSPS KAKENHI [16K05758, 19K05410, 26107532]
  3. Hosei University (Japan)

向作者/读者索取更多资源

Nitrogen and nickel are the main impurities in type Ib synthetic diamonds obtained under high pressure and high temperature conditions. The study found that an aluminum getter can prevent nitrogen from penetrating the diamond lattice.
Nitrogen and nickel are the main impurities in the type Ib synthetic diamonds obtained under high pressure and high temperature conditions using nickel-containing catalysts. Nitrogen enters the synthesized diamond from the air. The nickel/nitrogen ratio for the two types of diamonds, obtained with and without an aluminum getter that prevents the diamond crystal lattice from nitrogen penetration, was studied by electron spin resonance at 90 K.

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