期刊
MAGNETIC RESONANCE IN CHEMISTRY
卷 61, 期 3, 页码 180-183出版社
WILEY
DOI: 10.1002/mrc.5321
关键词
heterogeneous polarizing agent; Overhauser Dynamic Nuclear Polarization; polyaniline; scalar coupling
This article reports a scalar-coupling dominated H-1 O-DNP using polyaniline as a polarizing agent in an aqueous solution.
The Overhauser Dynamic Nuclear Polarization (O-DNP) of H-1 nuclei usually involves a dipolar coupling with the polarizing agent, whereas scalar coupling via hyperfine interactions are more common with C-13 nuclei. Here, we show a scalar-coupling dominated H-1 O-DNP, using polyaniline as a heterogeneous polarizing agent in an aqueous solution.
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