期刊
MACROMOLECULES
卷 55, 期 17, 页码 7785-7797出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.macromol.2c00777
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资金
- Center for Bioplastics and Biocomposites [DMR-1626315]
A series of novel poly(ethylene terephthalate) (PET) copolymers with improved properties were synthesized by incorporating bioadvantaged dimethyl 2,7-naphthalenedicarboxylate (2,7-N) as a comonomer. The addition of 2,7-N significantly enhanced the thermal, mechanical, and barrier properties of the copolymers, and the performance could be tuned by adjusting the loading of 2,7-N.
We report a series of novel poly(ethylene terephthalate) (PET) copolymers with improved properties through the incorporation of bioadvantaged dimethyl 2,7-naphthalenedicarboxylate (2,7-N) as a comonomer. PET is among the most commonly used engineering thermoplastics, ubiquitous in the food packaging industry. However, its application is limited by poor thermal (low T-g) and oxygen barrier performance. A series of poly(ethylene terephthalate-stat-2,7-naphthalate) copolymers were synthesized from ethylene glycol (EG), terephthalic acid (TPA), and 2,7-N via a standard two-step melt polycondensation reaction. The 2,7-N significantly improved the thermal, mechanical, and barrier properties. The glass transition temperature (T-g > 75.4 degrees C) and thermal stability (T-d,T-5% > 405.1 degrees C) of the copolymers increase monotonically with 2,7-N content, exceeding those of PET (T-g = 69.7 degrees C T-d,T-5% = 401.4 degrees C). Moreover, the mechanical properties and the crystallization behaviors are tunable through the 2,7-N loading. Composition-optimized copolymers showed an increase of 70% and 200% in elongation at break and tensile strength, respectively. In addition, the oxygen permeability value of the copolymers containing 20% 2,7-N loading fell to P-Oe = 0.0073 barrer, a 30% improvement over that of PET. These results illustrate that the novel substitution patterns offered by biobased chemicals can translate to performance advantages in packaging materials. Finally, the fundamental structure-property relationships connecting the bioadvantaged chemicals as the comonomers to the product performance were constructed as a guide for value-added renewable polymers in the future.
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