期刊
MACROMOLECULAR MATERIALS AND ENGINEERING
卷 307, 期 12, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/mame.202200455
关键词
bio-based materials; epoxidized linseed oil; epoxidized vegetable oils; epoxy thermoset; tannic acid
资金
- German Federal Ministry of Education and Research (BMBF) [FKZ: 03SF0577A]
- Projekt DEAL
This study introduces a fully bio-based epoxy thermoset using epoxidized linseed oil and tannic acid, which exhibits high glass transition temperature, stiffness, and strength, making it a potential bio-based substitute for petrochemical-based epoxy resins in high-performance applications.
Increasing demand for bio-based epoxy thermoset alternatives has risen in the last few years. Epoxidized vegetable oils (EVO) have attracted significant attention due to their bio-based, unharmful nature and high availability. This study proposes a fully bio-based epoxy thermoset based on epoxidized linseed oil (ELO) and tannic acid (TA). TA allows, with its high degree of functionality and aromatic structure as a curing agent for ELO, to create a fully bio-based polymer network with a high glass transition temperature (T-g), high stiffness, and high strength. A maximum T-g of 146 degrees C, a flexural modulus of 2986 MPa, and flexural strength of 72 MPa are obtained. The strong material properties of the TA/ELO thermoset expose its potential as a bio-based substitute for petrochemical-based epoxy resins for high-performance applications.
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