期刊
CARBOHYDRATE POLYMERS
卷 115, 期 -, 页码 516-524出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2014.08.084
关键词
Self-extinguishing; Phosphorylated chitin; Chitosan; Layer-by-Layer assembly method
资金
- National Basic Research Program of China (973 Program) [2012CB719701]
- National Key Technology RD Program [2013BAJ01B05]
- National Natural Science Foundation of China [21374111, 51303165]
The self-extinguishing coating, consisting of biobased chitin derivatives, phosphorylated chitin and deacetylated chitin (chitosan), was deposited on cotton fabrics via the Layer-by-Layer (LbL) assembled method. The content of phosphorylated chitin prepared on cotton fabrics surface is dependent on the bilayers' number and concentration of phosphorylated chitin. In the vertical flame test, the cotton fabric with 20 bilayers prepared at the high phosphorylated chitin concentration (2 wt%) could extinguish the flame. Microcombustion calorimetry result showed that all coated cotton fabrics showed lower peak heat-release rate and total heat-release values compared with that of the pure one. Thermogravimetric analysis result indicated that thermal and thermal oxidation stability of all coated cotton fabrics were enhanced in the high temperature range (400-700 degrees C). This work provided the flame retardant multilayer films based on fully biobased chitin derivatives on cotton fabrics to enhance its flame retardancy. (C) 2014 Elsevier Ltd. All rights reserved.
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