4.6 Article

High-performance medical-grade resin radically reinforced with cellulose nanofibers for 3D printing

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DOI: 10.1016/j.jmbbm.2022.105408

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Cellulose nanofibers (CNFs); Biomedical resin; Mechanical testing; 3D printing; Fractography; Vat photopolymerization

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This study reports the effect of adding Cellulose NanoFiber (CNF) to a medical-grade resin in Stereolithography (SLA) Additive Manufacturing (AM) technology, aiming to create an easily processable and highly stiff bio-compound. The mechanical, microhardness, and thermal properties of the fabricated nanocomposites were evaluated, and the results showed significant reinforcement with increased tensile strength. Microscopic and surface analysis were conducted to characterize the fractured tensile specimens.
The effect of Cellulose NanoFiber (CNF) addition to a medical-grade resin in Stereolithography (SLA) Additive Manufacturing (AM) technology is reported, aiming to elaborate an easily processable, highly stiff bio-compound. CNFs were shear stir blended at various weight ratios with liquid resin. The fabricated nano -composite materials were introduced in an SLA 3D printer for specimens manufacturing. The mechanical per-formance was studied according to international standards. Charpy Toughness and Vickers microhardness were calculated for all tested materials. A microscopic and surface analysis was conducted on fractured tensile specimens by Scanning Electron Microscopy (SEM) and Atomic Force Microscopy (AFM), respectively. The thermal and thermomechanical properties were investigated by Thermogravimetric Analysis (TGA), Differential Calorimetry (DSC), and Dynamic Mechanical Analysis (DMA). Significant reinforcement of the medical-grade nanocomposites is reported, with the highest values calculated to be at 1.0 wt% concentration (more than 100% at the tensile strength), while brittleness and rigidity were increased.

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