Interactions and corrosion mitigation prospective of pyrazole derivative on mild steel in HCl environment

The effectiveness of 1H-pyrazole-3,5-dicarboxylic acid 5-benzyl ester 3-phenyl ester (PCBPE) as a preventer for deterioration of IS 513 Gr. D steel in 1 M HCl medium is evaluated via weight loss, electrochemical impedance, and polarization techniques. Kinetic and thermodynamic parameters assessed the feasibility of the adsorption process at diverse temperatures. The inhibition action on mild steel has been enhanced with increasing PCBPE concentration. It is found from the polarization studies that PCBPE behaves as mixed type inhibitor in HCl medium. The adsorption process of PCBPE on mild steel surface from acid environment is favoured Langmuir adsorption isotherm. The shielding efficiency of PCBPE has been enhanced at elevated concentrations, and it has been diminished at amplified temperatures. The Atomic Force Microscope (AFM), Scanning Electron Microscope (SEM), and Energy Dispersive Spectrum (EDS) were used to establish a surface characterization of metal specimens. A quantum chemical analysis of electron density distributions in the highest occupied molecular orbital (HOMO) and lowest unoccupied molecular orbital (LUMO) demonstrated how the inhibitor undergoes adsorption on mild steel in 1 M HCl. All experimental findings substantiate the corrosion mitigation performance of PCBPE on mild steel in acidic environments.

Automated summary

The effectiveness of 1H-pyrazole-3,5-dicarboxylic acid 5-benzyl ester 3-phenyl ester (PCBPE) as a corrosion preventer for IS 513 Gr. D steel in 1 M HCl medium has been evaluated. The study found that increasing PCBPE concentration enhanced its inhibition action, and PCBPE exhibited mixed type inhibition behavior in HCl medium. The adsorption process of PCBPE on mild steel surface followed Langmuir adsorption isotherm.