期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 144, 期 41, 页码 18744-18749出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.2c07888
关键词
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资金
- JST PRESTO
- CREST (Japan)
- Iwatani Naoji Foundation
- International Collaborative Research Program of the Institute for Chemical Research at Kyoto University
- [JPMJPR16R7]
- [JPMJCR21Q1]
This study designed and synthesized an organometallic nickel complex containing thieno[3,2-b]thiophene units. Composite films of the nickel complex and polyvinylidene difluoride, prepared via a simple solution process, exhibited remarkably high n-type conductivity and air stability of the thermoelectric power factor. The introduction of thieno[3,2-b]thiophene core into the backbone of the nickel complex significantly influenced the orientation within the composite films, as indicated by grazing-incidence wide-angle X-ray diffraction analysis.
An organometallic nickel complex containing thieno[3,2-b]thiophene units was designed and synthesized. Composite films of the resulting nickel complex and polyvinylidene difluoride, which can be fabricated via a simple solution process under atmospheric conditions, exhibit remarkably high n-type conductivity (>200 S cm-1). Moreover, the thermoelectric power factor of the n-type composite film was proven to be air stable. A grazing-incidence wide-angle X-ray diffraction analysis indicated a significant impact of introducing the thieno[3,2-b]thiophene core into the backbone of the nickel complex on the orientation within the composite films.
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