☆ 4.8 Article

Synthesis of a Bench-Stable Manganese(III) Chloride Compound: Coordination Chemistry and Alkene Dichlorination

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

相关参考文献

注意：仅列出部分参考文献，下载原文获取全部文献信息。

Article Chemistry, Multidisciplinary

Elucidating the Mechanism of Excited-State Bond Homolysis in Nickel-Bipyridine Photoredox Catalysts

David A. Cagan et al.

Summary: This study investigates the mechanism of Ni(II)-bpy aryl halide complexes and finds that structural control can regulate the potential energy surfaces of metal-to-ligand and ligand-to-metal charge transfer excited states, facilitating the process of excited-state bond homolysis. This provides a rational approach to utilize photonic energy in synthetic chemistry.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Chemistry, Multidisciplinary

Catalytic Chemo-, Regio-, Diastereo-, and Enantioselective Bromochlorination of Unsaturated Systems Enabled by Lewis Base-Controlled Chloride Release

Alexandra E. Lubaev et al.

Summary: A new Lewis base-catalyzed bromochlorination strategy for unsaturated systems is described, which is mechanistically distinct and utilizes thionyl chloride as a latent chloride source in combination with as little as 1 mol % of triphenylphosphine or triphenylphosphine oxide as Lewis basic activators. This strategy exhibits excellent site selectivity and can access a wide variety of vicinal bromochlorides with high regio- and diastereoselectivity. The precision installation of Br, Cl, and I in various combinations is also demonstrated.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2022)

添加到收藏夹

Article Multidisciplinary Sciences

Merging shuttle reactions and paired electrolysis for reversible vicinal dihalogenations

Xichang Dong et al.

Summary: The study presents an electrochemically assisted shuttle (e-shuttle) paradigm for the facile and scalable interconversion of alkenes and vicinal dihalides, which can be used to synthesize dihalogenated molecules or recycle waste materials. The method demonstrates dibromination or dichlorination of alkenes using simple setup with inexpensive graphite electrodes. Additionally, it shows the complete dechlorination of hexachlorinated lindane to benzene using simple alkene acceptors in soil samples.

SCIENCE (2021)

添加到收藏夹

Article Chemistry, Multidisciplinary

Visible-Light-Induced Vicinal Dichlorination of Alkenes through LMCT Excitation of CuCl2

Pengcheng Lian et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

添加到收藏夹

Article Chemistry, Multidisciplinary

Preparation and structural studies of manganese polychloride anions in three metal charge states [(II), (III), (IV)]-their stereochemistries

Yashiro Rojas et al.

STRUCTURAL CHEMISTRY (2020)

添加到收藏夹

Review Biochemistry & Molecular Biology

How manganese empowered life with dioxygen (and vice versa)

Usha F. Lingappa et al.

FREE RADICAL BIOLOGY AND MEDICINE (2019)

添加到收藏夹

Article Chemistry, Physical

Catalytic Vicinal Dichlorination of Unactivated Alkenes

Jerome C. Sarie et al.

ACS CATALYSIS (2019)

添加到收藏夹

Article Chemistry, Physical

An Electrocatalytic Approach to the Radical Difunctionalization of Alkenes

Gregory S. Sauer et al.

ACS CATALYSIS (2018)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Iron(III) chloride and its coordination chemistry

Simon A. Cotton

JOURNAL OF COORDINATION CHEMISTRY (2018)

添加到收藏夹

Article Chemistry, Multidisciplinary

Electrocatalytic Radical Dichlorination of Alkenes with Nucleophilic Chlorine Sources

Niankai Fu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2017)

添加到收藏夹

Article Chemistry, Multidisciplinary

Mild, Redox-Neutral Formylation of Aryl Chlorides through the Photocatalytic Generation of Chlorine Radicals

Matthew K. Nielsen et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2017)

添加到收藏夹

Review Chemistry, Multidisciplinary

Catalytic, Stereoselective Dihalogenation of Alkenes: Challenges and Opportunities

Alexander J. Cresswell et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2015)

添加到收藏夹

Article Chemistry, Multidisciplinary

Trap-Free Halogen Photoelimination from Mononuclear Ni(III) Complexes

Seung Jun Hwang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Halogen Photoelimination from Monomeric Nickel(III) Complexes Enabled by the Secondary Coordination Sphere

Seung Jun Hwang et al.

ORGANOMETALLICS (2015)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Solvates of Manganese Trichloride Revisited - Synthesis, Isolation, and Crystal Structure of MnCl3(THF)3

Olaf Nachtigall et al.

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE (2015)

添加到收藏夹

Review Chemistry, Inorganic & Nuclear

Active sites and mechanisms of bioinspired oxidation with H2O2, catalyzed by non-heme Fe and related Mn complexes

Konstantin P. Bryliakov et al.

COORDINATION CHEMISTRY REVIEWS (2014)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Low-Spin Hexacoordinate Mn(III): Synthesis and Spectroscopic Investigation of Homoleptic Tris(pyrazolyl)borate and Tris(carbene)borate Complexes

Adam P. Forshaw et al.

INORGANIC CHEMISTRY (2013)

添加到收藏夹

Article Chemistry, Multidisciplinary

Simple Reagents for Direct Halonium-Induced Polyene Cyclizations

Scott A. Snyder et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2010)

添加到收藏夹

Article Chemistry, Inorganic & Nuclear

Synthesis, structure, and properties of low-spin manganese(III)-poly(pyrazolyl)borate complexes

Ferdaus Hossain et al.

INORGANIC CHEMISTRY (2007)

添加到收藏夹

Article Chemistry, Physical

High-spin chloro mononuclear MnIII complexes:: A multifrequency high-field EPR study

C Mantell et al.

CHEMPHYSCHEM (2005)

添加到收藏夹

© Peeref 2019-2024. All rights reserved.