Chain-to-Layer Dimensionality Engineering of Chiral Hybrid Perovskites to Realize Passive Highly Circular-Polarization-Sensitive Photodetection

Article Chemistry, Multidisciplinary

High Responsivity Circular Polarized Light Detectors based on Quasi Two-Dimensional Chiral Perovskite Films

Tianjun Liu et al.

Summary: A CPL detector based on quasi-2D chiral perovskite films is reported, which exhibits both a high dissymmetry factor and responsivity, showcasing the potential of chiral perovskites in CPL-dependent photonic technologies.

ACS NANO (2022)

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Article Materials Science, Multidisciplinary

Polar Photovoltaic Effect in Chiral Alternating Cations Intercalation-Type Perovskites Driving Self-Powered Ultraviolet Circularly Polarized Light Detection

Tingting Zhu et al.

Summary: By transforming RP-type perovskites, chiral-polar photovoltaic ACI perovskites with remarkable CPPE have been developed, paving the way for self-powered short-wave ultraviolet CPL detection.

ADVANCED OPTICAL MATERIALS (2022)

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Article Materials Science, Multidisciplinary

Tailoring the Distinctive Chiral-Polar Perovskites with Alternating Cations in the Interlayer Space for Self-Driven Circularly Polarized Light Detection

Wentao Wu et al.

Summary: In this study, two alternating cations were developed in the interlayer space of chiral-polar hybrid perovskites, allowing for high detectivity in circularly polarized light (CPL) detection. The chiral-polar structure of these perovskites enables self-driven CPL detection without an applied voltage, and they exhibit a fast response time.

ADVANCED OPTICAL MATERIALS (2022)

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Article Chemistry, Multidisciplinary

Chiral 1D perovskite microwire arrays for circularly polarized light detection

Yingjie Zhao et al.

Summary: High-performance circularly polarized light photodetectors were fabricated by using a special method, which possess excellent crystallinity and pure crystallographic orientation, and exhibit impressive stability under ambient conditions.

GIANT (2022)

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Article Chemistry, Multidisciplinary

Chiral Lead-Free Hybrid Perovskites for Self-Powered Circularly Polarized Light Detection

Dong Li et al.

Summary: Metal-halide perovskites have emerged as promising alternatives for CPL detection due to their CPL-sensitive property induced by chiral organics and efficient charge transport of inorganic frameworks. This study successfully developed lead-free halide double perovskites, demonstrating significant chirality and self-powered CPL detection capabilities. The research suggests that hybrid double perovskites can be promising photoelectronic candidates for exploring new green circularly polarized light-sensitive materials with high performance.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2021)

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Article Chemistry, Multidisciplinary

Alkyl-Aryl Cation Mixing in Chiral 2D Perovskites

Liang Yan et al.

Summary: The study presents a new type of 2D hybrid perovskites with a unique combination of chirality and alkyl-aryl functionality, determined by noncovalent intermolecular interactions in their crystal structures. The mixed-cation perovskites exhibit a circular dichroism distinct from purely chiral cation analogues, providing a new avenue for tuning the chiroptical properties of known chiral perovskites. Mixing chiral cations with achiral cations may offer a potential way to tailor the spin-based properties in 2D hybrid perovskites.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Review Chemistry, Multidisciplinary

Chiral Perovskites for Next-Generation Photonics: From Chirality Transfer to Chiroptical Activity

Sunihl Ma et al.

Summary: Organic-inorganic hybrid halide perovskites (OIHPs) are widely used in various applications due to their exceptional optoelectrical properties and structural flexibility. Despite intriguing chiral properties, the transfer mechanism from chiral molecules to achiral semiconductors and the origin of chiroptical activity are still not extensively studied. This comprehensive review discusses recent advances in chiroptical activities of chiral OIHPs and provides insight into the underlying chirality transfer mechanism.

ADVANCED MATERIALS (2021)

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Article Chemistry, Multidisciplinary

Chiral 2D-Perovskite Nanowires for Stokes Photodetectors

Yingjie Zhao et al.

Summary: High-performance Stokes-parameter photodetectors are realized based on solution-processed chiral-perovskite nanowire arrays, which exhibit responsive circularly polarized light and large polarized ratio to linearly polarized light due to chiral ammonium cations and strictly aligned nanowires. The detectors demonstrate promising applications towards polarization imaging with their small footprint and high performance.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Realization of vis-NIR Dual-Modal Circularly Polarized Light Detection in Chiral Perovskite Bulk Crystals

Yu Peng et al.

Summary: This study presents the visible-near-infrared dual-modal CPL-sensitive direct detection in bulk single crystals of two-dimensional chiral perovskite for the first time. By designing new chiral semiconductors with strong light-matter interaction, high detection performance is achieved.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2021)

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Article Chemistry, Multidisciplinary

Heterogeneous Integration of Chiral Lead-Chloride Perovskite Crystals with Si Wafer for Boosted Circularly Polarized Light Detection in Solar-Blind Ultraviolet Region

Xinyuan Zhang et al.

Summary: By growing chiral HOIP single crystals onto silicon wafers, a strong built-in electric field at the heterojunction is generated, providing a driving force for separating/transporting carriers under CPL excitation. The transfer of chirality and significant amplification of circular polarization sensitivity in the transport process lead to an anisotropy factor of up to 0.4 at zero bias, making it the highest among reported CPL-UV photodetectors. This integration of chiral HOIP crystals with silicon technology opens up possibilities for high-performance CPL detectors in the solar-blind UV region and other advanced optoelectronic devices.

SMALL (2021)

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Article Chemistry, Multidisciplinary

Great Amplification of Circular Polarization Sensitivity via Heterostructure Engineering of a Chiral Two-Dimensional Hybrid Perovskite Crystal with a Three-Dimensional MAPbI3 Crystal

Xinyuan Zhang et al.

Summary: The construction of a heterostructure crystal, integrating a chiral two-dimensional perovskite with its three-dimensional counterpart, significantly enhances circular polarization sensitivity for CPL detectors. This strategy allows for the creation of a CPL detector with a greatly amplified anisotropy factor, providing a novel approach to modulate circular polarization sensitivity in chiral hybrid perovskites for advanced chiroptical devices.

ACS CENTRAL SCIENCE (2021)

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Article Chemistry, Multidisciplinary

A Chiral Reduced-Dimension Perovskite for an Efficient Flexible Circularly Polarized Light Photodetector

Lin Wang et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2020)

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Review Nanoscience & Nanotechnology

Low-Dimensional Hybrid Perovskites for Field-Effect Transistors with Improved Stability: Progress and Challenges

Yuhang Liang et al.

ADVANCED ELECTRONIC MATERIALS (2020)

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Article Chemistry, Multidisciplinary

High-Performance Circularly Polarized Light-Sensing Near-Infrared Organic Phototransistors for Optoelectronic Cryptographic Primitives

Hyemi Han et al.

ADVANCED FUNCTIONAL MATERIALS (2020)

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Article Multidisciplinary Sciences

Direct detection of circular polarized light in helical 1D perovskite-based photodiode

A. Ishii et al.

SCIENCE ADVANCES (2020)

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Article Multidisciplinary Sciences

Circularly polarized light detection using chiral hybrid perovskite

Chao Chen et al.

NATURE COMMUNICATIONS (2019)

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Article Chemistry, Multidisciplinary

Bulk Photovoltaic Effect in a Pair of Chiral-Polar Layered Perovskite-Type Lead Iodides Altered by Chirality of Organic Cations

Po Jung Huang et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Article Chemistry, Multidisciplinary

A Highly Luminescent Chiral Tetrahedral Eu4L4(L′)4 Cage: Chirality Induction, Chirality Memory, and Circularly Polarized Luminescence

Yanyan Zhou et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2019)

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Review Nanoscience & Nanotechnology

Dimensional tailoring of hybrid perovskites for photovoltaics

Giulia Grancini et al.

NATURE REVIEWS MATERIALS (2019)

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Article Chemistry, Multidisciplinary

Chiral 2D Perovskites with a High Degree of Circularly Polarized Photoluminescence

Jiaqi Ma et al.

ACS NANO (2019)

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Article Chemistry, Multidisciplinary

Chiral Excitonic Organic Photodiodes for Direct Detection of Circular Polarized Light

Matthias Schulz et al.

ADVANCED FUNCTIONAL MATERIALS (2019)

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Article Chemistry, Physical

High performance low-dimensional perovskite solar cells based on a one dimensional lead iodide perovskite

Chunqing Ma et al.

JOURNAL OF MATERIALS CHEMISTRY A (2019)

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Article Chemistry, Multidisciplinary

Structural Diversity in White-Light-Emitting Hybrid Lead Bromide Perovskites

Lingling Mao et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Chemistry, Multidisciplinary

Chiroptical Activity from an Achiral Biological Metal-Organic Framework

Li-Li Xu et al.

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY (2018)

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Article Optics

Spin control in reduced-dimensional chiral perovskites

Guankui Long et al.

NATURE PHOTONICS (2018)

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Article Chemistry, Inorganic & Nuclear

Synthetic Control on Structure/Dimensionality and Photophysical Properties of Low Dimensional Organic Lead Bromide Perovskite

Muhammed P. U. Haris et al.

INORGANIC CHEMISTRY (2018)

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Review Multidisciplinary Sciences

Dimensionality engineering of hybrid halide perovskite light absorbers

Peng Gao et al.

NATURE COMMUNICATIONS (2018)

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Article Optics

Multichannel vectorial holographic display and encryption

Ruizhe Zhao et al.

LIGHT-SCIENCE & APPLICATIONS (2018)

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Article Multidisciplinary Sciences

One-dimensional organic lead halide perovskites with efficient bluish white-light emission

Zhao Yuan et al.

NATURE COMMUNICATIONS (2017)

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Article Chemistry, Multidisciplinary

A new class of chiral semiconductors: chiral-organic-molecule-incorporating organic-inorganic hybrid perovskites

Jihoon Ahn et al.

MATERIALS HORIZONS (2017)

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Article Chemistry, Multidisciplinary

Searching for promising new perovskite-based photovoltaic absorbers: the importance of electronic dimensionality

Zewen Xiao et al.

MATERIALS HORIZONS (2017)

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Article Chemistry, Multidisciplinary

Emergent Properties of an Organic Semiconductor Driven by its Molecular Chirality

Ying Yang et al.

ACS NANO (2017)

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Article Chemistry, Multidisciplinary

A Photoferroelectric Perovskite-Type Organometallic Halide with Exceptional Anisotropy of Bulk Photovoltaic Effects

Zhihua Sun et al.

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION (2016)

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Article Chemistry, Physical

Can Pb-Free Halide Double Perovskites Support High-Efficiency Solar Cells?

Christopher N. Savory et al.

ACS ENERGY LETTERS (2016)

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Article Multidisciplinary Sciences

Electron-hole diffusion lengths > 175 μm in solution-grown CH3NH3PbI3 single crystals

Qingfeng Dong et al.

SCIENCE (2015)

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Circularly polarized light detection with hot electrons in chiral plasmonic metamaterials

Wei Li et al.

NATURE COMMUNICATIONS (2015)

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Article Physics, Applied

Unusual defect physics in CH3NH3PbI3 perovskite solar cell absorber

Wan-Jian Yin et al.

APPLIED PHYSICS LETTERS (2014)

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Article Chemistry, Physical

Organometallic Halide Perovskites: Sharp Optical Absorption Edge and Its Relation to Photovoltaic Performance

Stefaan De Wolf et al.

JOURNAL OF PHYSICAL CHEMISTRY LETTERS (2014)

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Article Chemistry, Physical

Engineered materials for all-optical helicity-dependent magnetic switching

S. Mangin et al.

NATURE MATERIALS (2014)

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Quantum entanglement between an optical photon and a solid-state spin qubit

E. Togan et al.

NATURE (2010)

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Inorganic-organic hybrid materials incorporating primary cyclic ammonium cations: The lead iodide series

David G. Billing et al.

CRYSTENGCOMM (2007)

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Kramers-Kronig transformation for optical rotatory dispersion studies

PL Polavarapu

JOURNAL OF PHYSICAL CHEMISTRY A (2005)

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Chain-to-Layer Dimensionality Engineering of Chiral Hybrid Perovskites to Realize Passive Highly Circular-Polarization-Sensitive Photodetection

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