期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 144, 期 37, 页码 16726-16731出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.2c07135
关键词
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资金
- Samsung Electronics, Veteran research grant [2019R1A2C2004259]
- Basic Science Research Institute Fund [2021R1A6A1A10042944]
- Korea government (MSIT) [2020R1C1C1008785, 2021R1A2C2010972, 2020R1A5A1019141]
- National Research Foundation of Korea [2021R1A2C2010972, 2020R1C1C1008785] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
In this study, a conductive two-dimensional metal-organic framework (MOF) thin film was successfully synthesized using single-step all-vapor-phase chemical vapor deposition (CVD). The synthesized Cu-3(C6O6)(2) thin film showed high crystallinity with edge-on orientation. Cu-3(C6O6)(2) thin film-based microdevices were fabricated and exhibited an electrical conductivity of 92.95 S/cm. The synthesis of conductive MOF thin films by all-vapor-phase CVD offers a platform for fundamental studies on their physical properties and potential practical applications.
We demonstrated the synthesis of a conductive two-dimensional metal-organic framework (MOF) thin film by single-step all-vapor-phase chemical vapor deposition (CVD). The synthesized large-area thin film of Cu-3(C6O6)(2) has an edge-on orientation with high crystallinity. Cu-3(C6O6)(2) thin film-based microdevices were fabricated by e-beam lithography and had an electrical conductivity of 92.95 S/cm. Synthesis of conductive MOF thin films by the all-vapor-phase CVD will enable fundamental studies of physical properties and may help to accomplish practical applications of conductive MOFs.
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