期刊
JOURNAL OF POWER SOURCES
卷 543, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jpowsour.2022.231821
关键词
All-solid-state capacitor; Oxide electrolyte; Carbon nanotube; Solid interface
资金
- JSPS KAKENHI [18H05255, 19H05816]
A highly deformable lithium-ion conducting oxide solid electrolyte was studied to enhance the electrochemical performance of all-solid-state capacitors. By incorporating this solid electrolyte between electrode layers, low resistance and improved capacitance were achieved.
The development of all-solid-state capacitors (ASSCs) based on inorganic solid electrolytes (SEs) with high thermal stability is desired. However, because of their high cell resistance, such capacitors have lower capacitances and rate capabilities than conventional electric double-layer capacitors (EDLCs) that use aqueous solutions and organic liquid electrolytes. The high resistance is caused by the mechanical and electrochemical properties of the SE. In this study, a highly deformable Li-ion conducting oxide SE was investigated to improve the electrochemical performance of ASSCs. Bulk-type symmetric ASSCs, with a 33Li(3)BO(3)center dot 33Li(2)SO(4)center dot 33Li(2)CO(3) (LBSC) SE layer between two electrode layers of an LBSC-CNT composite, showed low resistance and were operable at 100-300 degrees C. Additionally, the highest capacitance at the highest current reported for ASSCs till date was achieved. The highly deformable SE will facilitate the design of ASSCs and expand the potential range of applications of EDLCs.
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