4.5 Article

Synthesis and Characterisation of a Hterobimetallic N-heterocyclic Carbene Rhodium Ruthenium Complex as Catalyst for Transfer Hydrogenation

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JOURNAL OF ORGANOMETALLIC CHEMISTRY
卷 979, 期 -, 页码 -

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ELSEVIER SCIENCE SA
DOI: 10.1016/j.jorganchem.2022.122498

关键词

Rhodium; Ruthenium; Heterobimetallic; Abnormal N-heterocyclic carbene; Crystal structure; Transfer hydrogenation

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The heterobimetallic N-heterocyclic dicarbene (NHDC) rhodium ruthenium complex was synthesized via transmetallation and tested as a catalyst in the transfer hydrogenation reaction of acetophenone. The complex exhibited high turnover frequency and good catalytic performance.
The heterobimetallic N-heterocyclic dicarbene (NHDC) rhodium ruthenium complex [Ru(OAc)(Mes-NHC-methyl-PPh2)(Mes-aNHC-methyl-PPh2)RhCl(cod)] ( 4 ) is obtained from a mixed normal/abnormal bis-NHC ruthenium complex via transmetallation by addition of [RhCl(cod)](2) in THF at 40 degrees C, applying Ag2O as base. Crystallization is achieved by layering a solution of 4 in THF with Et2O. The complex is applicable as a catalyst in the transfer hydrogenation (TH) reaction of acetophenone, exhibiting a turnover frequency (TOF) of 6 700 h(-1) with 80% conversion after 25 min (0.10 mol% catalyst, (PrOH)-Pr-i, 80 degrees C, 2.00 mol% (NaOPr)-O-i). These results are compared to an analogous iridium ruthenium NHDC complex. (C) 2022 Elsevier B.V. All rights reserved.

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