期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01998
关键词
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资金
- National Natural Science Foundation of China
- Natural Science Foundation of Jiangsu Province
- Lvyang Jinfeng Talents Attracting Plan
- [22101249]
- [BK20200918]
A highly efficient palladium-catalyzed allenamide allylic alkylation of sulfenate anions under mild conditions is demonstrated, providing a practical protocol to access various sulfoxide-containing heterocyclic compounds. The transformation features a broad substrate scope, good functional group tolerance, easy scalability, and convenient synthetic transformation.
A highly efficient palladium-catalyzed allenamide allylic alkylation of sulfenate anions under mild conditions is demonstrated. The present methodology provides a practical protocol to access various sulfoxide-containing heterocyclic compounds. The salient features of this transformation include a broad substrate scope, good functional group tolerance, easy to scale-up, and ready synthetic transformation.
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