4.7 Article

Synthesis of Phenols from Aryl Ammonium Salts under Mild Conditions

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JOURNAL OF ORGANIC CHEMISTRY
卷 -, 期 -, 页码 -

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AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01133

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  1. National Natural Science Foundation of China [22071056, 22001070]

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A general method for synthesizing phenols from electron-deficient aryl ammonium salts or heteroaryl ammonium salts was developed using hydroxide surrogates such as benzaldehyde oxime, acetohydroxamic acid, and hydroxylamine hydrochloride, resulting in yields of 20-98%.
A general method for the synthesis of phenols from electron-deficient aryl ammonium salts or heteroaryl ammonium salts under mild conditions was developed. Benzaldehyde oxime, acetohydroxamic acid, and hydroxylamine hydrochloride were investigated as hydroxide surrogates respectively. With these hydroxide surrogates, a series of phenols were prepared in yields of 20-98%.

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