4.7 Article

Eosin Y-Catalyzed Visible-Light-Induced Hydroperfluoroalkylation of Electron-Deficient Alkenes

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JOURNAL OF ORGANIC CHEMISTRY
卷 87, 期 21, 页码 14923-14929

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AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01827

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  1. MEXT, Japan
  2. [19K05472]
  3. [21H05219]

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The eosin Y-catalyzed hydroperfluoroalkylation of electron-deficient alkenes is a selective and efficient reaction that proceeds smoothly under visible light irradiation. This reaction allows for the use of various perfluoroalkyl bromides and electron-deficient olefins, and all required chemicals are readily available and safe.
The eosin Y-catalyzed hydroperfluoroalkylation of electron-deficient alkenes is described herein. The reaction proceeded smoothly under visible light irradiation and selectively afforded a hydroperfluoroalkylated product. Various perfluoroalkyl bromides and electron-deficient olefins can be used in this reaction, and all chemicals required for this reaction are safe and readily available.

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