期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.2c01405
关键词
-
资金
- SERB, DST, Government of India [EEQ/2019/000031]
- UGC
In this study, cyclic diaryliodonium salts were developed as biarylating agents for C(sp3)-H functionalization, using 8-methyl quinoline as the intrinsic directing group. The oxidant-free reaction resulted in a wide range of biarylated products with iodo functionality, which can be further functionalized. Furthermore, intramolecular C(sp3)-H functionalization under palladium-catalyzed conditions produced fluorene derivatives with excellent yields.
Herein, we have developed the cyclic diaryliodonium salts as biarylating agents in the C(sp3)-H functionalization using 8-methyl quinoline as the intrinsic directing group. The oxidant-free reaction produces a vast array of the biarylated products with iodo functionality that can be further functionalized. Additionally, intramolecular C(sp3)-H functionalization in a stepwise manner under palladium-catalyzed conditions produced the fluorene derivatives in excellent yields.
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