4.6 Article

Corrosion protection properties of poly((benzoyl phenyl) methacrylate-co-methoxy ethylmethacrylate) coating on mild steel

期刊

JOURNAL OF MOLECULAR STRUCTURE
卷 1264, 期 -, 页码 -

出版社

ELSEVIER
DOI: 10.1016/j.molstruc.2022.133186

关键词

Synthesis; Copolymer coatings; Corrosion; Potentiodynamic polarization; EIS

资金

  1. Science & Engineering Research Board (SERB) , New Delhi [PDF/2020/001818, SQUID-1983-TS-4044]
  2. University Grants Commission (UGC), New Delhi, India [39-808/2010 (SR)]
  3. University Grants Commission (UGC)

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The copolymer of benzoylphenyl methacrylate and methoxyethyl methacrylate was synthesized and its thermal stability and corrosion protection efficiency on mild steel were investigated. The electrochemical results confirmed the good protective effect of the copolymer coating on the metal surface.
The copolymer, poly(BPM-CO-MOEMA) has been synthesized from different monomer feed ratios of benzoylphenyl methacrylate (BPM) and methoxyethyl methacrylate (MOEMA) was achieved using the free radical solution polymerization technique. The thermal stability of the synthesized copolymers was studied by using TGA and DSC. The molecular weight of the copolymer was determined by GPC. The corrosion protection efficiency of the mild steel specimens coated with different mole ratios of the copolymer has been investigated using electrochemical techniques like EIS and potentiodynamic polarization studies in 1 M H2SO4. The observation of electrochemical results confirmed that the copolymer coating shows good protection efficiency for mild steel in the corrosive media. The surface and morphological investigations also confirm the barrier effect of the copolymer film on the metal surface against the invasion of corrosive ions. (C) 2022 Elsevier B.V. All rights reserved.

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