Tannic acid (TA)-based coating modified membrane enhanced by successive inkjet printing of Fe3+ and sodium periodate (SP) for efficient oil-water separation

Wettability of membrane is of vital importance for treatment of oily wastewater. In recent years, hydrophilic modifications based on plant polyphenol have been widely investigated to enhance the anti-fouling property of membranes due to their mild conditions, versatility and low cost. However, there are still some problems in improving raw material utilization and hydrophilicity. Herein, a facile method was proposed to optimize tannic acid (TA)-based membrane modification process by synergistically inducing TA deposition by Fe3+ and SP with the assistance of inkjet printing. The hydrophobicity of polyvinylidene fluoride (PVDF) membrane was converted to hydrophilicity (WCA = 34.6 degrees) and underwater oleophobicity (UOCA = 144.4 degrees) in very short time (10 min). The optimum PVDF/Fe-TA-SP422 membrane possessed high flux (4968.4-7340.4 L m(-2) h(-1).bar(-1)) for a number of oil/water emulsions with high separation efficiency (>98%), outperforming most state-of-the-art membranes for oil-water separation. Furthermore, the optimized membrane displayed not only high antifouling property and reusability with flux recovery ratio of 89.1%-98.0% after eight-cycle filtration, but also desired stability under near neutral pH conditions during long-term running. The combination of inkjet printing method with these materials proposed in this study is convenient, efficient and low cost, and the prepared membranes are versatility, providing novel insights into preparation of high efficiency membranes for oily wastewater treatment.

Automated summary

The wettability of membranes is crucial for treating oily wastewater. This study proposes a facile method using inkjet printing to optimize the tannic acid-based membrane modification process. By synergistically inducing tannic acid deposition with Fe3+ and SP, the hydrophobic polyvinylidene fluoride (PVDF) membrane is converted to a hydrophilic and underwater oleophobic membrane with high flux and separation efficiency. The optimized membrane also exhibits high antifouling property, reusability, and stability under near neutral pH conditions.