4.7 Article

Regulating bifunctional flower-like NiFe2O4/graphene for green EMI shielding and lithium ion storage

期刊

JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 127, 期 -, 页码 48-60

出版社

JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2022.04.010

关键词

NiFe2O4; Graphene; EMI shielding; Anode; Lithium-ion batteries

资金

  1. National Natural Science Foun-dation of China [52177014, 51977009, 11774027, 51132002, 51372282, 52071192, 51804191]
  2. Basic Research Project of Shanxi Province [202103021223342]

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This study fabricated a novel flower-like NiFe2O4/graphene composite as EMI shielding material and anode material for lithium-ion batteries. The composite showed excellent EMI shielding performance and electrochemical performance, which could be attributed to the structure regulation and synergistic effect of graphene and NiFe2O4.
Environment and energy are the eternal hot topics in the world, multiloculated microscale materials have attracted great attention in the field of electromagnetic interference (EMI) shielding and lithium ions storage. Herein, a novel flower-like NiFe2O4/graphene composite with adjustable structure was fabricated as EMI shielding material and anode material of lithium-ion batteries. NiFe2O4/graphene composite is a potential green EMI shielding material. The EMI shielding effectiveness (SE) increases with the increase of graphene content in NiFe2O4/graphene composite, and the total EMI SE of NiFe2O4/graphene with 73.6 wt.% graphene increases from 26.5 to 40.6 dB with the increase of frequency in 2-18 GHz. Furthermore, it exhibits long-life and large capacity lithium storage performance at high current density. The capacity reaches 732.79 mAh vl after 100 cycles at 0.1 A g(-1), recovering to more than 139% from the minimum capacity value. After 300 cycles at 0.5 A g(-1), the capacity increases to 688.5 mAh g(-1). The initial capacities at 2 and 5 A g(-1) are 704.9 and 717.8 mAh g(-1), and remain 297.9 and 203.2 mAh g(-1) after 1000 cycles. The distinguished EMI shielding performance and electrochemical performance are mainly ascribed to the structure regulation of NiFe2O4 /graphene composite, as well as the synergistic effect of graphene and NiFe2O4. This research opens up infinite opportunities for the application of multifunctional and interdisciplinary materials. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.

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