期刊
JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY
卷 127, 期 -, 页码 236-244出版社
JOURNAL MATER SCI TECHNOL
DOI: 10.1016/j.jmst.2022.04.009
关键词
Supercapacitor; ZnCo2O4; NiCo2O4; Energy density; Excellent conductivity; High capacitance
In this study, a self-supporting electrode based on vertically grown two-dimensional/two-dimensional NiCo2O4/ZnCo2O4 hierarchical flakes was designed, using graphene and carbon nanotubes as the carbon-based conductive substrate. The experimental results showed that the electrode exhibited high capacitance and cycling stability, making it suitable for high-efficiency electrochemical energy storage devices.
The energy storage device has been urgently studied and developed to meet the increasing demand for energy and sustainable development. Due to the excellent conductivity of graphene and high performance of ZnCo2O4 and NiCo2O4, we design a self-supporting electrode based on vertically grown twodimensional/two-dimensional (2D/2D) NiCo2O4/ZnCo2O4 hierarchical flakes on the carbon-based conductive substrate (NiCo2O4/ZnCo2O4@graphene/carbon nanotubes, NZ@GC). The density functional theory calculations indicate that the high OH - adsorption capacity of the NiCo2O4/ZnCo2O4 nanosheets can significantly enhance the electrochemical reaction activity. NZ@GC shows a high capacitance of 1128.6 F g(-1) at 1 A g(-1). The capacitance retains 84.0% after 6000 cycles even at 10 A g(-1). A hybrid supercapacitor is fabricated using NZ@GC and activated carbon, exhibiting a large energy density of 50.8 W h kg(-1) at the power density of 800 W kg(-1). After 9000 charge/discharge cycles, the supercapacitor still has 86.1% capacitance retention. The NZ@GC film has showed the potential as promising electrodes in high efficiency electrochemical energy storage devices. (C) 2022 Published by Elsevier Ltd on behalf of The editorial office of Journal of Materials Science & Technology.
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