期刊
JOURNAL OF MAGNETISM AND MAGNETIC MATERIALS
卷 557, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jmmm.2022.169481
关键词
Manganites; Magnetocaloric effect; Nanocrystalline
资金
- Department of Atomic Energy (DAE), Govt. of India
In this study, the magnetic properties and magnetocaloric effect of two nanocrystalline La0.17Ca0.83MnO3 samples were investigated. The nanocrystalline compounds showed significant changes in physical properties compared with the bulk counterpart, due to their proximity to the phase boundary. Additionally, the signature of canted magnetic phase was observed in the nanocrystalline sample through magnetocaloric effect study.
In this present study we report the Magnetic properties and magnetocaloric effect of two nanocrystalline La0.17Ca0.83MnO3 samples with average particle size ~40 nm and ~70 nm. According to the reported phase diagram, the bulk compound lies near the phase boundary between charge ordered antiferromagnetic and canted antiferromagnetic state. In contrast to the bulk counterpart, the significant effect of the phase boundary was observed on the physical properties of nanocrystalline compounds. Moreover, the signature of canted magnetic phase in nanocrystalline sample was probed through magnetocaloric effect study.
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