The insecticidal activity of pyridylpyrazole-4-carboxamides containing 1,3,4-oxadiazole-ring against diamondback and noctuid moths was evaluated, and it was found that substitutions on the 1,3,4-oxadiazole moiety were crucial for determining the bioactivity.
The insecticidal activity of 1,3,4-oxadiazole-ring containing pyridylpyrazole-4-carboxamides against diamondback (Plutella xylostella) and noctuid (Spodoptera frugiperda) moths were evaluated. Only substitutions on the 1,3,4-oxadiazole moiety dictated bioreactivity, with 8q2 m-CF3Ph being the most effective against Plutella xylostella, showing 80%-93% mortality at a concentration of 0.5-500 mu g ml(-1) while the others remained inactive or less active (highest mortality being 63%). The larvicidal activity against Spodoptera frugiperda was inferior compared with that of Plutella xylostella, with the highest mortality being 33%. A crystal of 8q5 was obtained and analyzed, revealing the effects of intramolecular H-bonds and intermolecular pi-pi interactions.
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