4.3 Article

Dehydrofluorination reactions at Lewis acidic ACF in the presence of HSnBu3

期刊

JOURNAL OF FLUORINE CHEMISTRY
卷 263, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jfluchem.2022.110046

关键词

Lewis acids; Fluorine; Dehydrofluorination; Aluminum; Tin hydride

资金

  1. Deutsche Forschungsgemeinschaft (DFG, German Research Foundation)
  2. Chinese Scholarship Council
  3. [387284271 - SFB 1349]

向作者/读者索取更多资源

Dehydrofluorination reactions of fluoroalkanes were catalyzed by nanoscopic aluminum chlorofluoride (ACF, AlClxF3-x, x approximate to 0.05-0.3) in the presence of HSnBu3. Mechanistic studies suggest an initial interaction of ACF with the tin hydride instead of the fluoroalkane.
Dehydrofluorination reactions of fluoroalkanes were catalyzed by the highly Lewis acidic nanoscopic aluminum chlorofluoride (ACF, AlClxF3-x, x approximate to 0.05-0.3) in the presence of HSnBu3 as hydrogen source. Mechanistic studies suggest an initial interaction of ACF with the tin hydride instead of the fluoroalkane. MAS NMR studies provided information on the interaction of HSnBu3 with the ACF surface as well as the capability of ACF to perform C-F bond activation of fluoroalkanes without additives.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.3
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据