4.5 Article

NiCr-Cl LDH/rGO Composite as Anode Material for Sodium-Ion Batteries

期刊

JOURNAL OF ELECTRONIC MATERIALS
卷 51, 期 11, 页码 6067-6075

出版社

SPRINGER
DOI: 10.1007/s11664-022-09911-1

关键词

Layered double hydroxides; reduced graphene oxide; composite; anode materials; sodium-ion batteries

资金

  1. National Natural Science Foundation of China [51674147]
  2. Natural Science Foundation of the Higher Education Institutions of Jiangsu Province [19KJB480013]
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD)
  4. Postgraduate Research and Practice Innovation Program of Jiangsu Province

向作者/读者索取更多资源

Layered double hydroxides (LDHs) have high theoretical specific capacity and simple preparation method, but suffer from slow diffusion kinetics and electrochemical instability. By fabricating Cl--intercalated NiCr LDH/rGO composite, the cycling performance and rate capability are improved, showing superior Na+ ion storage performance.
Layered double hydroxides (LDHs) have attracted increasing attention as anode materials for sodium-ion batteries (SIBs) due to their high theoretical specific capacity and simple preparation method. However, LDHs used as anode materials for SIBs still suffer from sluggish diffusion kinetics and huge volume change during the charge and discharge process, resulting in poor cycling performance and rate capability. Therefore, we fabricated a Cl--intercalated NiCr layered double hydroxide/reduced graphene oxide (NiCr-Cl LDH/rGO) composite as an anode material for SIBs. Compared with pure NiCr-CO3 LDH and NiCr-CO3 LDH/rGO electrodes, the NiCr-Cl LDH/rGO electrode exhibited excellent cycling performance and rate capability, with the highest specific capacity of 218 mAh g(-1) at current density of 100 mA g(-1) for 200 cycles and 219 mAh g(-1) at current density of 2.0 A g(-1). The superior Na+ ion storage performance is attributed to the large interlayer spacing and the good electrical conductivity and flexibility of rGO. This work could provide a new path for constructing LDH-based composites as anode materials for SIBs in the field of energy storage.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.5
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据