期刊
JOURNAL OF ELECTROANALYTICAL CHEMISTRY
卷 924, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jelechem.2022.116857
关键词
Supercapacitors; Beetroot; Redox additives; Energy storage; Activated carbon
资金
- CSIR [31/20 (0174) /2018-EMR-I]
- CSIR-CECRI [CECRI/PESVC/Pubs/2022-055]
In this research, activated carbon derived from beetroot was used as the electrode material for supercapacitors, with the incorporation of redox additives to enhance electrochemical performance in aqueous electrolytes. The use of hydroquinone as a redox additive resulted in a high specific capacity for the prepared electrode, as well as superior power and energy density compared to traditional electrolytes.
Supercapacitors are presumed to be ideal for electrochemical energy storage high power applications because they are an intermediate between conventional capacitors and batteries. Various bio-derived activated carbon was venerated for enhanced supercapacitor application and the electrochemical performance of carbon-based materials in aqueous electrolytes was further enhanced to a greater extent with the incorporation of redox addi-tives. In this work, the activated carbon obtained from beetroot is explored as the electrode material for super -capacitors with redox additives in electrolytes. The chemical functionalities and elements present in the prepared activated carbon were confirmed using FT-IR and XPS, respectively. The electrochemical energy stor-age behavior of the prepared activated carbon was analyzed with hydroquinone (HQ) as a redox additive. The specific capacity of the prepared electrode in 0.01 M HQ/H2SO4 at 3 A/g is 2589 C/g. The calculated power and energy density of the fabricated symmetric cell with HQ/H2SO4 at 3 A/g are 2356 W/kg and 36 Wh/ kg, which is superior to the mere 1 M H2SO4 electrolyte with the gravimetric power and energy density of 1800 W/kg and 13.5 Wh/kg, respectively.
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