Use of phase angle in alternating voltammetry on redox self-assembled monolayers with intermolecular interactions

We present a methodology based on the study of the frequency dependence of the phase angle in Alternative Voltammetry to estimate the standard electrochemical rate constant for heterogeneous electron transfer reac-tions in the case of strong intermolecular interactions occur between the redox forms.This work is a follow-up to our previous study which was dedicated only to the study of peak currents.

Automated summary

This methodology is based on the frequency dependence of the phase angle in Alternative Voltammetry to estimate the standard electrochemical rate constant for heterogeneous electron transfer reactions with strong intermolecular interactions occurring between the redox forms.