Enhancing the oxidative desulfurization efficiency of cobalt-loaded-porous carbon catalyst via nitrogen doping on carbon support

Melamine (M)-incorporated bimetallic (Zn/Co)-azolate framework-6s (M(x)@BM6s) (with wide M-contents) composites were firstly synthesized via an in-situ method and used as a precursor to derive Co/N-enriched porous carbon (M(x)@BMC6s) via pyrolysis. Very small Co-nanoparticles (4-10 nm) uniformly distributed on highly porous carbon with much N-doping were obtained from M(x)@BM6s. The developed Co-based materials with high N-content were used as catalysts for heterogeneous oxidative desulfurization (ODS) of liquid model fuel, critical for the environment and the petroleum industry. M(x)@BMC6s (with various N-contents), especially the M(10)@BMC6 (obtained from M(10)@BM6 with 10% M), were more competitive in ODS than orther tested Cobased catalysts (without or with less N-sites) and comparable to the reported catalysts to date. For example, the turnover frequency of M(10)@BMC6 was 61.1 h-1 and ~10 times that of Co/activated carbon. Additionally, the good reactivity of M(10)@BMC6 with adequate reusability might be understood by the good dispersion of small Co-nanoparticles. Importantly, dominant role of the doped N-species on carbon, by enhancing the synergy between Co- and N-species, was firstly suggested in this study. Finally, incorporation of N-sites in the carbon support for Co-nanoparticles can enhance the ODS performance, thus being suggested as an effective way to develop oxidation catalysts with outstanding performance.

Automated summary

Melamine-incorporated bimetallic azolate framework-6s composites were synthesized and used as precursor to obtain Co/N-enriched porous carbon via pyrolysis. The resulting Co-based materials showed excellent catalytic performance in oxidative desulfurization due to the presence of small Co nanoparticles and doped N-species on carbon support.