期刊
JOURNAL OF INORGANIC AND ORGANOMETALLIC POLYMERS AND MATERIALS
卷 26, 期 5, 页码 1053-1060出版社
SPRINGER
DOI: 10.1007/s10904-016-0429-0
关键词
Coordination polymers; Transition metals; Hydrogen bonds; Crystal structure; Magnetic properties
资金
- Special Funds of Guangdong College Students' scientific and Technological Innovation Cultivation [pdjh2016b0547]
- Distinguished Young Talents in Higher Education of Guangdong Province [2014KQNCX222]
- Natural Science Foundation of Guangdong Province [2015A030310407]
- characteristics of innovative projects in Colleges and universities in Guangdong Province [2015KTSCX156]
- Training Plan of Guangdong Province Outstanding Young Teachers in Higher Education Institutions [YQ2015168]
- Natural Science Foundation of Zhaoqing University [201532]
- JSPS KAKENHI [15K05445]
- Grants-in-Aid for Scientific Research [15K05445] Funding Source: KAKEN
Two new transition metal-based coordination polymers, [Cu(fdc)(dmbpy)(H2O)](n) (1) {[Ni-2(fdc)(2)(bipy)(2)(H2O)(4)]center dot(H2O)(2)}(n) (2) (fdca = 2,5-furandicarboxylic acid, dmbpy = 3,3'-dimethyl-4,4'-bipyridine, bipy = 4,4'-bipyr idine) have been synthesized under the same reaction conditions (H2O, pH 7-8, and 130 degrees C) and were structurally characterized. 1 is a ladder chain, whereas 2 shows a 2D (4,4) network. Both 1 and 2 are further connected into 3D structures through hydrogen bonds. Furthermore, the magnetic properties of 1 and 2 are also investigated.
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