期刊
JOURNAL OF CATALYSIS
卷 413, 期 -, 页码 1028-1033出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcat.2022.08.013
关键词
Levulinic acid; Hydrogenation; Titanium; Gamma-valerolactone; Angelica lactone; Homogeneous catalysis
资金
- CONACyT [770960, A1 -S-7657]
- DGAPA-UNAM
A titanium-based catalytic system using a commercially available titanocene complex was developed for the hydrogenation of levulinic acid to y-valerolactone. The method achieved excellent yields under mild reaction conditions. Key mechanistic insights into the main species involved in the catalytic cycle were also documented.
A titanium-based catalytic system using the commercially available titanocene complex [Cp2TiCl2], was developed for hydrogenation of levulinic acid to y-valerolactone (GVL), using mild reaction conditions (100 & DEG;C and 100 psi) and excellent yields (> 99 %). Key mechanistic insights, including the main species involved in the catalytic cycle, are also documented.(c) 2022 Elsevier Inc. All rights reserved.
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