期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 915, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.165353
关键词
Lithium-ion batteries; Anode materials; N-doped carbon coating; Hollow structure
资金
- Graduate Science and Technology Project Funding Project of the North University of China [20200806]
In this study, g-C3N4-derived CN coating wrapped concave hollow ZnO@C dodecahedrons were synthesized and used as anode materials for lithium-ion batteries. The designed structure and coating improved the conductivity, cycle stability, and lithium storage capacity of the batteries. The results demonstrate the potential of this design concept for other lithium storage materials and nitrogen doping regulation.
Currently, conversion-type lithium-ion battery (LIB) anode materials suffer from low conductivity and poor Li+ storage stability. Hence, g-C3N4-derived CN coating wrapped concave hollow ZnO@C dodecahedrons (ZnO@C@CN) were synthesized in this study and was used to address these challenges. The high-content pyrrolic-N-doped ZnO@C@CN-4 was precisely regulated by the solid-phase method, which can furnish complementary appearing defects, vacancies, and lithium storage sites. In addition, the CN coating and concave hollow structure improved the cycle stability and lithium storage capacity of the device. As LIBs anodes, the initial discharge specific capacity of ZnO@C@CN-4 was 1769.4 mA h g(-1), and the reversible discharge capacity was 546.2 mA h g(-1) after 1000 cycles at 1.0 A g-1. The rate performance data demonstrated that a capacity of 326.5 mA h g(-1) capacity was achieved at a current density of 2.0 A g(-1), and a high capacity of 678.1 mA h g(-1) was still maintained after 100 cycles from high to low current. The design concept of this work can be extended to the other lithium storage materials and would also provide new insights into the regulation of nitrogen doping. (C) 2022 Elsevier B.V. All rights reserved.
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