UV-enhanced highly sensitive ammonia sensing properties based on 2DPI/In2O3 heterostructure at room temperature

The UV-enhanced sensing performance of the two-dimensional polyimidefindium oxide (2DPI/In2O3) based sensor towards NH3 was investigated at room temperature of 25 degrees C. The 2DPI/In2O3 composite materials with hydrogen bond were synthesized by hydrothermal method, which is sensitive to NH3 in the absence or presence of UV illumination. The microstructure, morphology and constituent elements of the prepared samples were characterized by SEM, TEM, XRD, XPS, FT-IR and UV-visible analysis. The as-prepared 2DPI/In2O3 based sensor shows the best sensing performance compared to those of pure 2DPI and pure In2O3 sensors. In terms of the sensitivity of the 2DPI/In2O3 based sensor, the synergistic effect between 2DPI and In2O3 leads to an enhancement of three times response of the composite sensors under UV illumination compared with the response of composite sensors without UV illumination. Particularly, the response time and recovery time of the 2DPI/In2O3 based sensor towards 1 ppm NH3 are shortened by 10 s and 20 s under 365 nm UV illumination, respectively. The significant enhancement in sensing performance is due to the formation of the heterojunction between 2DPI and In2O3. Besides, 2DPI acts as photocatalytic promoter in the 2DPI/In2O3 composite. The 2DPI/In(2)O(3)based sensor is a promising candidate for UV-assisted NH3 detection at room temperature. (C) 2022 Elsevier B.V. All rights reserved.

Automated summary

The UV-enhanced sensing performance of a 2DPI/In2O3 based sensor for NH3 at room temperature was investigated. The composite material was synthesized using a hydrothermal method and showed sensitivity to NH3 with or without UV illumination. Characterization techniques confirmed the superior performance of the 2DPI/In2O3 sensor compared to pure 2DPI or In2O3 sensors. The presence of the 2DPI-In2O3 heterojunction and the photocatalytic promotion of 2DPI contribute to the enhanced sensing performance.