期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 915, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.165450
关键词
Silicon carbide; Au-Pt; Photocatalysis; Water splitting; Hydrogen
资金
- Fundamental Research Funds for the Central Universities of China [2020RC004]
- National Natural Science Foundation of China [51902017, 51972017, 61875009]
In this study, a plasmonic catalyst Au-Pt-SiC was prepared by introducing Pt-Si bonds on the SiC surface, creating an excellent channel for efficient photo-electron transfer. The localized surface plasmon resonance effect of Au further activated the Pt-Si bonds and motivated a high-efficient photo-electron transport channel among Au, Pt, and SiC. The LSPR of Au also enhanced light absorption and broadened the range of light absorption.
The localized surface plasmon resonance effect (LSPR) with kinetic energies and interfacial transfer dynamics can highly improve the separation of photo-generated carriers. We demonstrate here that a plasmonic catalyst Au-Pt-SiC has been prepared by a facile reduction-photo-deposition technique. The Pt-Si bond is formed on the SiC surface to construct an excellent channel for accelerating photo-electrons transfer from SiC to Pt. The LSPR of Au with electrons-deficiency property further activates the anchored Pt-Si bond, and motivates an oriented high-efficient photo-electrons transport channel among the Au, Pt and SiC. This channel accelerates the excited electrons in SiC to transfer to cocatalysts and thus improves the photo-generated charge carriers separation. The LSPR of Au also harvests light energy efficiently to broaden the light absorption range. Consequently, the rate of photocatalytic water reduction for H-2 is enhanced to 2248.5 mu L h(-1) g(-1) in Au-Pt-SiC, 2.1 times higher than that of the individual Pt loading. (C) 2022 Elsevier B.V. All rights reserved.
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