4.7 Article

Honeycomb-like SnS2/graphene oxide composites for enhanced microwave absorption

期刊

JOURNAL OF ALLOYS AND COMPOUNDS
卷 915, 期 -, 页码 -

出版社

ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.165405

关键词

SnS2 @GO; Honeycomb-like structure; Heterogeneous interface; Dielectric property; Microwave absorption

资金

  1. Key Deployment Projects of the Chinese Academy of Sciences [ZDRW-CN-2021-3-2-02]
  2. Science and Technology Service Network Initiative regional Key Project of the Chinese Academy of Sciences [KFJ-STS-QYZD-2021-07-0 02]
  3. Zhejiang Provincial Key Research and Development Projects [2021C01033]

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Honeycomb-like SnS2/GO composites were fabricated via a facile chemical bath deposition method for optimizing the microwave absorption performances. The composites exhibited excellent microwave absorption ability with a wide effective absorption bandwidth (EAB) and strong absorption, which could be attributed to the strong interfacial polarization and good impedance matching. The SnS2 content in the composites could be adjusted to tune the impedance matching and attenuation constant.
Achieving the broad effective absorption bandwidth (EAB), strong absorption capacity and thin matching thickness are still a huge challenge for the dielectric loss-type microwave absorbers. Here, the honeycomblike SnS2/ graphene oxide (GO) composites are fabricated via a facile chemical bath deposition method to optimize the microwave absorption performances. The 2D SnS2 nanosheets are uniformly and vertically grown on the GO sheets, forming a highly open hierarchical network, which can be beneficial to enhance the multiple scatterings and reflections of incident electromagnetic wave. Meanwhile, the impedance matching (Z) and attenuation constant (alpha) of composites are well-tuned by changing the SnS2 content in the composites. When the GO sheets are just completely coated by SnS2 nanosheets, the SnS2/GO composite exhibits excellent microwave absorption ability with the minimum reflection loss (RLmin) of - 59.2 dB and EAB of 5.4 GHz (12.3-17.7 GHz) at the thickness of only 1.45 mm, which is mainly ascribed to the strong interfacial polarization and good impedance matching. This work provides a significant guidance to achieve excellent absorption performance with broad EAB and strong absorption for dielectric loss-type absorbers. (c) 2022 Published by Elsevier B.V.

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