期刊
JOURNAL OF ALLOYS AND COMPOUNDS
卷 922, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jallcom.2022.166306
关键词
One -pot Synthesis; MoSe 2; Nanoparticles; Anode; Lithium; sodium ion batteries
资金
- Key Projects for the Excellent Talent Foundation of Education Department of Anhui Province [gxyqZD2020039]
- High-level Scientific Research Foundation for the Introduction of Talent [2020rcjj27, 2020rcjj26]
- Natural Science Foundation of the Education Department of Anhui Province [KJ2020A0109]
Highly-uniform MoSe2 nanoparticles were successfully synthesized with the addition of PVP, which contributes to the prevention of over-agglomeration of nanosheets and enhancement of various performances, including cycle stability and rate performance.
Molybdenum diselenide (MoSe2) have attracted much attention as an anode material for lithium/sodium ion batteries due to its specific layered structure. Here, highly-uniform MoSe2 nanoparticles are successfully synthesized via a one-pot hydrothermal method with addition of polyvinyl pyrrolidone (PVP) following by calcination treatment. PVP serves as a surfactant preventing the over-agglomeration of MoSe2 nanosheets and contributing to the well-organized accumulation of MoSe2 nanosheets into nanoparticles. When evaluated as anode for lithium ion batteries, the MoSe2 nanoparticles show enhanced cycle stability and rate performance comparing to the MoSe2 bulk prepared without addition of PVP. After 200 cycles, the MoSe2 nanoparticles remain a specific capacity of 573.9 mAh g-1 at a rate of 200 mA g-1. Meanwhile, MoSe2 nanoparticles also display good sodium storage performance. Under the current density of 500 mA g-1, MoSe2 nanoparticles exhibit reversible capacity of 374.9 mA h g-1 after 100 cycles. (c) 2022 Elsevier B.V. All rights reserved.
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