4.7 Review

A short review on generation of green fuel hydrogen through water splitting

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Article Chemistry, Physical

An efficient B/Na co-doped porous g-C3N4 nanosheets photocatalyst with enhanced photocatalytic hydrogen evolution and degradation of tetracycline under visible light

Xianhu Chi et al.

Summary: By utilizing element doping and morphology control strategies, B/Na co-doped porous carbon nitride nanosheets were prepared, exhibiting exceptional photocatalytic hydrogen generation and pollutant removal properties. This provides a new approach for the preparation of semiconductor photocatalysts with superior performance.

APPLIED SURFACE SCIENCE (2022)

Article Chemistry, Physical

Up-conversion fluorescent carbon quantum dots decorated covalent triazine frameworks as efficient metal-free photocatalyst for hydrogen evolution

Yueling Chen et al.

Summary: This study successfully enhanced the activity of photocatalytic hydrogen production by constructing carbon quantum dots/covalent triazine-based framework (CQDs/CTF) non-metallic photocatalyst. Carbon quantum dots played an important role in electron capture and the separation of photoinduced electron-hole pairs. Additionally, the up-conversion fluorescent characteristics of CQDs broadened the visible-light response range and improved solar energy utilization efficiency.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Interface engineering of Ni0.85Se/Ni3S2 nanostructure for highly enhanced hydrogen evolution in alkaline solution

Dongdong Shi et al.

Summary: The Ni0.85Se/Ni3S2 heterostructure synthesized through interface engineering demonstrates superior HER electrocatalytic performance in alkaline media, with lower overpotential and better stability compared to Ni3S2. The enhanced HER activity of this heterostructure is mainly attributed to the modulation of surface electronic structure and the construction of heterointerface between Ni0.85Se and Ni3S2.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

MoS2/CdS rod-like nanocomposites as high-performance visible light photocatalyst for water splitting photocatalytic hydrogen production

Hongming Zhao et al.

Summary: This study demonstrates a high-performance visible-light-driven photocatalyst for water splitting H-2 production. The MoS2/CdS nanocomposites exhibit excellent H-2 evolution rates and apparent quantum efficiency due to the modified surface of CdS nanorods with MoS2 nanosheets.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Multidisciplinary

An in situ generated 3D porous nanostructure on 2D nanosheets to boost the oxygen evolution reaction for water-splitting

Wenli Yu et al.

Summary: In this work, 2D nanosheets decorated with a 3D porous nanostructure, known as FeCoNi-NS-ACVs, were developed. FeCoNi-NS-ACVs exhibited superhydrophilic and excellent electroconductivity properties, and showed outstanding electrocatalytic performances and durability for both OER and overall water-splitting reactions.

NANOSCALE (2022)

Article Chemistry, Multidisciplinary

Electron Irradiation Induces the Conversion from 2H-WSe2 to 1T-WSe2 and Promotes the Performance of Electrocatalytic Hydrogen Evolution

Xiaoqing Yue et al.

Summary: This study converted 2H phase tungsten selenide into 1T phase tungsten selenide through 1 MeV electron irradiation to improve its electrocatalytic performance, providing a new method for introducing the ideal 1T phase in similar materials.

ACS SUSTAINABLE CHEMISTRY & ENGINEERING (2022)

Article Materials Science, Multidisciplinary

Corrosive-coordinate engineering to construct 2D-3D nanostructure with trace Pt as efficient bifunctional electrocatalyst for overall water splitting

Zhi Chen et al.

Summary: The study introduced a novel 2D-3D nanostructure with metal hydroxides and Prussian blue analogus for efficient hydrogen evolution and oxygen evolution. The new material exhibited excellent performance in electrochemical reactions in both deionized water and seawater, showcasing remarkable durability and efficiency for overall water splitting.

SCIENCE CHINA-MATERIALS (2022)

Review Chemistry, Physical

Single-atom catalysts for photocatalytic hydrogen evolution: A review

Lilai Sun et al.

Summary: The application of hydrogen energy is crucial for addressing the challenges of fossil energy depletion and carbon emissions. Photocatalytic hydrogen evolution is considered a green and clean method for obtaining hydrogen. Single-atom catalysts (SACs) have emerged as promising cocatalysts with abundant active sites and efficient reaction mechanisms in the fields of energy and environmental science. This review summarizes the advances of SACs in photocatalytic hydrogen evolution.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Photocatalytic hydrogen evolution reaction with high solar-to-hydrogen efficiency driven by the Sb2S3 monolayer and RuI2/Sb2S3 heterostructure with solar light

Fei Wang et al.

Summary: The feasibility and solar-to-hydrogen efficiency of the photocatalytic hydrogen evolution reaction with Sb2S3 monolayers and RuI2/Sb2S3 heterostructure were studied using first-principles calculations. The Sb2S3 monolayers showed high efficiency in hydrogen generation, and the RuI2/Sb2S3 heterostructure can drive the HER through the Z-scheme. This study is important for understanding and improving the efficiency of photocatalytic hydrogen evolution reaction.

JOURNAL OF POWER SOURCES (2022)

Article Chemistry, Applied

Recent advances in non-metal doped titania for solar-driven photocatalytic/photoelectrochemical water-splitting

Ying-Ying Wang et al.

Summary: Non-metal doping can enhance the visible light activity of TiO2-based photocatalysts by reducing the band gap and suppressing the recombination of electron-hole pairs. Different non-metal elements such as N, C, B, S, P, Halogens act as dopants to improve the efficiency of photocatalysis and photoelectrochemical water splitting.

JOURNAL OF ENERGY CHEMISTRY (2022)

Article Chemistry, Physical

N, P-codoped molybdenum carbide nanoparticles loaded into N, P-codoped graphene for the enhanced electrocatalytic hydrogen evolution

Peng Zuo et al.

Summary: A ternary phosphomolybdic acid-polyethyleneimine/graphene oxide nanocomposite was developed as a precursor for the controllable growth of molybdenum carbide nanostructure on graphene and the doping of N and P atoms. The hybrid exhibited remarkable electrocatalytic activity and high stability for hydrogen evolution reaction, making it a promising electrocatalyst.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Metal-organic frameworks derived N,S,O-doped carbon sheets coated CoP/Co3S4 hybrids for enhanced electrocatalytic hydrogen evolution reaction

Wei Jiang et al.

Summary: Evidence shows that embedding metal-based hybrids into a carbon matrix is a promising method for enhancing the efficiency and reducing the cost of electrocatalysts. In this study, a CoP/Co3S4 hybrid embedded into N, S, O-doped carbon sheets (CoP/Co3S4@NSOC) was constructed using a metal-organic framework (MOF) as a precursor. The resulting material exhibited favorable morphology, hetero-atom doping, and graphite carbon, enabling efficient electron and mass transfer. The intrinsic activity of CoP and Co3S4 further enhanced the electrocatalytic performance, with CoP/Co3S4@NSOC demonstrating the lowest overpotential for the hydrogen evolution reaction among all tested precursors. Additionally, the material showed long-term stability over 60 hours, indicating its potential as a robust MOF-derived electrocatalyst.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Chemistry, Physical

Enhanced hydrogen evolution by rGO decorated copper nickel tin sulphide (CNTS-rGO) in acidic medium by water splitting

I Sheebha et al.

Summary: A simple hydrothermal synthesis method was used to prepare CNTS-rGO micro flowers with excellent structural and optical properties, demonstrating promising HER performance.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2022)

Article Materials Science, Multidisciplinary

The role of lone-pair electrons on electrocatalytic activity of copper antimony sulfide nanostructures

Poulami Hota et al.

MATERIALS CHEMISTRY AND PHYSICS (2022)

Article Energy & Fuels

Two-dimensional AuSe/SnSe heterostructure for solar photocatalytic hydrogen evolution reaction with Z-scheme

Qi-Kang Yin et al.

Summary: The study explores the solar photocatalytic hydrogen evolution reaction driven by a 2D AuSe/SnSe heterostructure, demonstrating increased efficiency in photocatalytic water decomposition for hydrogen production through a direct Z-scheme.

SOLAR ENERGY MATERIALS AND SOLAR CELLS (2022)

Article Chemistry, Physical

In situ phase-reconfiguration to synthesize Ru, B co-doped nickel phosphide for energy-efficient hydrogen generation in alkaline electrolytes

Yonglong Wang et al.

Summary: This study develops efficient and durable samples for electrocatalytic monolithic hydrolysis and demonstrates their excellent catalytic performance in the oxygen evolution reaction, hydrogen evolution reaction, and urea oxidation reaction, as well as their ability to drive water splitting at low voltage. The findings highlight the potential application of these samples in storing hydrogen energy from sustainable sources.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Chemistry, Physical

Ru, B Co-doped hollow structured iron phosphide as highly efficient electrocatalyst toward hydrogen generation in wide pH range

Zixuan Wang et al.

Summary: This study synthesized B and Ru co-doped iron hollow spheres for efficient electrocatalytic hydrogen evolution reaction. The as-synthesized catalyst exhibited excellent performance with low overpotentials in acidic, neutral, and alkaline electrolytes, demonstrating its potential for energy conversion and storage applications.

JOURNAL OF MATERIALS CHEMISTRY A (2022)

Article Electrochemistry

Magic hybrid structure as multifunctional electrocatalyst surpassing benchmark Pt/C enables practical hydrazine fuel cell integrated with energy-saving H2 production

Ziyun Li et al.

Summary: This study presents a rational design of a hybrid catalyst structure with low Pt loading, which demonstrates superior multifunctional catalytic activity for various electrochemical reactions in alkaline conditions. Theoretical calculations reveal that the metal-carbon hybrid plays a crucial role in modulating kinetic behavior and achieving the energetic requirements for multiple electrocatalysis. The catalyst shows inspiring practical utility for sustainable H2 production.

ESCIENCE (2022)

Article Electrochemistry

Phosphated IrMo bimetallic cluster for efficient hydrogen evolution reaction

Xu Guo et al.

Summary: In this study, phosphated IrMo bimetallic clusters supported by macroporous nitrogen-doped carbon were developed as highly efficient alkaline HER catalysts. By tuning the electronic structure and utilizing atom synergies, these catalysts improved the adsorption and desorption abilities of the reactant and product, resulting in low overpotential and high mass activity even with a small amount of Ir. The multilevel design strategy demonstrated in this study effectively improves noble metal atom efficiency.

ESCIENCE (2022)

Article Chemistry, Inorganic & Nuclear

Phosphorus doped two-dimensional CoFe2O4 nanobelts decorated with Ru nanoclusters and Co-Fe hydroxide as efficient electrocatalysts toward hydrogen generation

Wenli Yu et al.

Summary: In this study, a novel and efficient HER catalyst is developed by introducing phosphorus, Ru, and CoFe hydroxide clusters onto 2D CoFe2O4 nanobelts. The modified catalyst exhibits excellent HER performance and long-term stability, showing potential applications in large-scale hydrogen generation.

INORGANIC CHEMISTRY FRONTIERS (2022)

Article Materials Science, Multidisciplinary

Z-Scheme photocatalytic solar-energy-to-hydrogen conversion driven by the HfS2/SiSe heterostructure

Chun-Fang Zhang et al.

Summary: The feasibility and efficiency of photocatalytic solar-energy-to-hydrogen conversion using a direct Z-scheme driven by a HfS2/SiSe heterostructure were investigated. The results showed that the band alignment and built-in electric field of the heterostructure make it suitable for the photocatalytic hydrogen evolution reaction. The study also examined the photoelectronic performance of the monolayers and the effects of strain on the photocatalytic properties.

JOURNAL OF MATERIALS CHEMISTRY C (2022)

Article Chemistry, Physical

Remarkable visible-light induced hydrogen generation with ZnIn2S4 microspheres/CuInS2 quantum dots photocatalytic system

Onur Cavdar et al.

Summary: A new and active material, ZnIn2S4 microspheres decorated with CuInS2 quantum dots, was successfully synthesized using a hydrothermal method for the first time. The introduction of an optimum amount of CuInS2 quantum dots significantly increased the photocatalytic H-2 generation rate under visible light irradiation, showing strong photoactivity and high apparent quantum efficiency in the extended visible range.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Review Chemistry, Multidisciplinary

Transition-Metal Carbides as Hydrogen Evolution Reduction Electrocatalysts: Synthetic Methods and Optimization Strategies

Han Zhang et al.

Summary: Hydrogen energy is considered a primary choice for future energy supply due to its strengths of zero carbon emission and high gravimetric energy density. Electrochemical water splitting is a promising strategy for sustainable hydrogen production, but a key challenge for its large-scale application is the availability of low-cost and efficient electrocatalysts for the hydrogen evolution reaction (HER). This review summarizes recent advances in synthetic methods and optimization strategies of transition-metal carbide (TMC) electrocatalysts, and also proposes perspectives for the development of novel efficient TMC-based catalysts.

CHEMISTRY-A EUROPEAN JOURNAL (2021)

Article Chemistry, Physical

Recent advances on electrocatalytic and photocatalytic seawater splitting for hydrogen evolution

Yuan Yao et al.

Summary: Hydrogen is a clean and renewable energy source, and the direct utilization of seawater for hydrogen production can reduce costs and promote rational exploitation of seawater resources. Advanced technologies such as photocatalysis, electrocatalysis, and photoelectrocatalysis have shown significant potentials in seawater splitting for hydrogen production.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Review Chemistry, Physical

Review and comparison of various hydrogen production methods based on costs and life cycle impact assessment indicators

Mengdi Ji et al.

Summary: Hydrogen is a clean and renewable secondary energy source which many countries are pursuing to combat global warming. This paper provides an overview of various hydrogen production technologies, including fossil fuel or biomass-based production, electrolysis, and thermochemical cycles. While the mainstream approach involves obtaining hydrogen from natural gas and coal, electrolysis and thermochemical cycles coupled with new energy sources show considerable potential for development.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Chemistry, Physical

Halogen Edge-Passivated Antimonene Nanoribbons for Photocatalytic Hydrogen Evolution Reaction with High Solar-to-Hydrogen Conversion

Miao Liu et al.

Summary: The photocatalytic hydrogen evolution reaction by antimonene nanoribbon with halogen edge passivation shows enhanced performance under tensile strain larger than 4%, and the different halogen edges have varying effects on the electronic properties. The nanoribbons with hydrogen edge passivation exhibit valence band and conduction band maximums matching the redox potentials for water-splitting HER, indicating their potential as preferable candidates for solar light photocatalytic water splitting for hydrogen production.

JOURNAL OF PHYSICAL CHEMISTRY C (2021)

Review Energy & Fuels

The Sabatier Principle in Electrocatalysis: Basics, Limitations, and Extensions

Hideshi Ooka et al.

Summary: The Sabatier principle, which emphasizes on the optimal binding energy between catalyst and reactant, has evolved from an empirical principle to a quantitative predictive tool thanks to the success of density functional theory (DFT). Understanding and overcoming the limitations and challenges of the Sabatier principle in its current thermodynamic context is crucial for the development of next-generation electrocatalysts.

FRONTIERS IN ENERGY RESEARCH (2021)

Article Chemistry, Physical

Recent development in electrocatalysts for hydrogen production through water electrolysis

Shams Anwar et al.

Summary: Hydrogen is a carbon-free alternative energy source for future energy frameworks, offering environmental friendliness and high energy density. Water electrolysis is a sustainable method to produce high purity hydrogen, and developing electrocatalysts for this process is crucial. While precious metals are traditionally used for electrocatalysis, non-precious metal-based electrocatalysts have advantages in cost and eco-friendliness, but further research is needed for their development.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Review Chemistry, Physical

Transition metal sulfides for electrochemical hydrogen evolution

Hamid Ghorbani Shiraz et al.

Summary: Hydrogen is considered the most promising zero-carbon fuel for the future, with the hydrogen evolution reaction attracting significant attention as a critical step in hydrogen technology and economy. Transition metal disulfides have emerged as a potential candidate for promoting hydrogen evolution due to their low cost and engineering versatility, with studies showing that manipulating their structure and morphology can enhance their proton reduction performance.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Review Chemistry, Physical

Review on hydrogen production photocatalytically using carbon quantum dots: Future fuel

Yogeshwari Vyas et al.

Summary: Carbon quantum dots (CQDs) are zero-dimensional nanoparticles that have gained attention for their potential applications in water splitting for hydrogen production. They exhibit excellent optical and electronic properties, high stability, low toxicity, and can be used for catalytic hydrogen gas production from water under sunlight.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Chemistry, Physical

Carbon supported Ni3N/Ni heterostructure for hydrogen evolution reaction in both acid and alkaline media

Dhandapani Balaji et al.

Summary: The study introduced a special route to construct carbon-supported Ni3N/Ni as an effective electrocatalyst for the hydrogen evolution reaction, showing superior electrical conductivity and charge transfer rate. By enhancing the electronic structure through intrinsic active sites, the Ni3N/Ni@C750 degrees C composite demonstrated enhanced electrocatalytic behavior in both acid and alkaline electrolytes.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2021)

Article Electrochemistry

Ni2P/NiMoP heterostructure as a bifunctional electrocatalyst for energy-saving hydrogen production

Tongzhou Wang et al.

Summary: An effective approach is introduced in this study to replace the anodic oxygen evolution reaction with a urea oxidation reaction, significantly decreasing the cell voltage for hydrogen production. The Ni2P/NiMoP catalyst shows impressive activity for both hydrogen evolution and oxygen evolution during hydrogen production. The introduction of urea results in a significant reduction in oxidation voltage, and the two-electrode electrolyzer with Ni2P/NiMoP catalyst exhibits excellent long-term durability.

ESCIENCE (2021)

Article Chemistry, Multidisciplinary

A platinum nanoparticle doped self-assembled peptide bolaamphiphile hydrogel as an efficient electrocatalyst for the hydrogen evolution reaction

Deepak K. K. Kori et al.

Summary: The study successfully embedded platinum nanoparticles into the hydrogel formed by peptide bolaamphiphile self-assembly, showing efficient catalytic activity for the hydrogen evolution reaction. Pt6@hydrogel exhibited low overpotential and reasonable Tafel slope in sulfuric acid solution, as well as electrocatalytic activity in alkaline and neutral pH solutions.

NANOSCALE ADVANCES (2021)

Article Materials Science, Multidisciplinary

Two-dimensional heterostructures of AuSe/SnS for the photocatalytic hydrogen evolution reaction with a Z-scheme

Qi-Kang Yin et al.

Summary: 2D heterostructures with the Z-scheme can greatly enhance the recombination of photogenerated charge pairs, improve photocatalytic reactions, and achieve high solar-to-hydrogen energy conversion efficiency.

JOURNAL OF MATERIALS CHEMISTRY C (2021)

Article Materials Science, Multidisciplinary

Surface-Modified Covalent Organic Polymer for Metal-Free Electrocatalytic Hydrogen Evolution Reaction

Anirban Pradhan et al.

Summary: Rapid global warming has driven a shift towards green renewable energy sources, and the metal-free TFPB-PAM electrocatalyst has shown excellent performance in hydrogen production through water splitting, highlighting its significant potential in the field of renewable energy.

ACS APPLIED POLYMER MATERIALS (2021)

Article Chemistry, Multidisciplinary

Amine-functionalized multi-walled carbon nanotubes (EDA-MWCNTs) for electrochemical water splitting reactions

Shankar S. Narwade et al.

Summary: This study presents a highly efficient and inexpensive metal-free electrocatalyst for hydrogen evolution reaction (HER) and oxygen evolution reaction (OER). The ethylene diamine decoration on multi-walled carbon nanotubes provides nitrogen-rich nanomaterials, offering a promising approach for replacing fossil fuels.

NEW JOURNAL OF CHEMISTRY (2021)

Review Chemistry, Multidisciplinary

Recent Advances in Electrocatalytic Hydrogen Evolution Using Nanoparticles

Jing Zhu et al.

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Fabrication of rGO/CdS@2H, 1T, amorphous MoS2 heterostructure for enhanced photocatalytic and electrocatalytic activity

Yue Zhao et al.

INTERNATIONAL JOURNAL OF HYDROGEN ENERGY (2020)

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Application of Co3O4-based materials in electrocatalytic hydrogen evolution reaction: A review

Junqing Ma et al.

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Hua Tang et al.

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Wan Zhao et al.

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Mohammad Ziaur Rahman et al.

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Chalcogens doped BaTiO3 for visible light photocatalytic hydrogen production from water splitting

Hai-Cai Huang et al.

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Shu-Wen Sun et al.

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Pt4 cluster catalyzes H2 generation from an H2O molecule

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Pristine and Se-/In-doped TlAsS2 enhance the solar energy-driven water splitting for hydrogen generation

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Nanostructured Bi2O3@TiO2 photocatalyst for enhanced hydrogen production

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Hybrid of AgInZnS and MoS2 as efficient visible-light driven photocatalyst for hydrogen production

Ting Huang et al.

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Hydrogen generation from water molecule with Pt7 clusters

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Ruthenium/Graphene-like Layered Carbon Composite as an Efficient Hydrogen Evolution Reaction Electrocatalyst

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CuCo Hybrid Oxides as Bifunctional Electrocatalyst for Efficient Water Splitting

Min Kuang et al.

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Porous MoO2 Nanosheets as Non-noble Bifunctional Electrocatalysts for Overall Water Splitting

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Extraction of H2 from H2O molecule using a small Al6Si cluster

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In-situ S-doped porous anatase TiO2 nanopillars for high-efficient visible-light photocatalytic hydrogen evolution

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