期刊
INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
卷 47, 期 97, 页码 41087-41096出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.ijhydene.2022.09.168
关键词
Nickel-metal hydride batteries; Cathode materials; Nickel hydroxide; Ni-Fe layered double hydroxide
资金
- National Natural Science Foundation of China [51801100, 52071177, 21975125, 52171214]
- Six Talent Peaks Project in Jiangsu Province [2018, XNY-020]
- Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions
A series of flower-like Ni-Fe layered double hydroxides (LDHs) were successfully synthesized and used as cathode materials for nickel-metal hydride batteries (Ni-MH batteries). The 4Ni-Fe LDH electrode displayed the highest high-rate discharge property and the most excellent cycling performance. The improvement can be attributed to the formation of LDHs, as well as their unique morphology and enlarged interlayer spacing.
A series of 3D flower-like Ni-Fe layered double hydroxides (LDHs) were synthesized successfully and used as the cathode materials for nickel-metal hydride battery (Ni-MH battery). The 4Ni-Fe LDH electrode (Ni/Fe molar ratio = 4:1) displays the highest high-rate discharge property and the most excellent cycling performance. The discharge capacity of the 4Ni-Fe LDH electrode can reach up to 291.3 mAh/g at a discharge rate of 200 mA/g and which delivers a high capacity retention of 98.9% over 200 cycles. In contrast, the pure Ni(OH)2 electrode only has a capacity of 243 mAh/g, and after 100 cycles the capacity retention is just 73.4%. The above improvement can be ascribed to the formation of Ni-Fe LDHs which can consolidate the stability of a-Ni(OH)2 in the KOH solution. In addition, the unique flower-like morphology and the enlarged interlayer spacing also paly important role to promote ion transmission and charge transfer. Considering the competitive price of Fe, 3D flower-like Ni-Fe LDH may be a more economical choice for the cathode material of Ni-MH batteries. (c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
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