4.7 Article

Electrochemical study of highly durable cathode with Pt supported on ITO-CNT composite for proton exchange membrane fuel cells

期刊

出版社

ELSEVIER SCIENCE INC
DOI: 10.1016/j.jiec.2016.07.039

关键词

Proton exchange membrane fuel cells; Cathode; Catalyst support; Pt; Indium tin oxide; Carbon nanotube

资金

  1. U.S. Department of Energy (DOE) Office of Energy Efficiency and Renewable Energy Fuel Cell Technologies Program
  2. DOE [DE-AC05-76L01830]
  3. National Research Foundation of Korea [NRF-2014R1A1A2057667]

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In this paper, we describe a highly stable cathode containing a Pt catalyst supported on an indium tin oxide (ITO) and carbon nanotube (CNT) composite. The dependence of cathode performance and durability on the ITO content and the diameter of the CNTs were investigated by electrochemical techniques. The cathode with 30 wt% ITO and CNTs with diameters 10-20 nm in the composite offered preferred locations for Pt stabilization and was very resistant to carbon corrosion (i.e., 82.7% ESA retention and 105.7% mass activity retention after an accelerated stress test for 400 h). (C) 2016 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.

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