期刊
CARBOHYDRATE POLYMERS
卷 122, 期 -, 页码 367-375出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.carbpol.2014.10.020
关键词
Nanocellulose; Cellulose nanocrystals; Iridescence; Pigment grinding
资金
- Papeteries du Leman
- French National Reserach Agency (ANRT)
- TekLiCell cluster
- Rhone-Alpes region
- LGP2 , LabEx Tec 21 (Investissements d'Avenir) [ANR-11-LABX-0030]
- Energies du Futur and PolyNat Carnot Institutes
- Investissements d'Avenir [ANR-11-CARN-007-01, ANR-11-CARN-030-01]
A simple method to produce biobased iridescent pigments from cellulose nanocrystal (CNC) films is reported. The process consists of forming nanostructured films from a CNC liquid-crystalline suspension and an appropriate dry grinding. The features of the iridescent pigments are described; they have a flake-like morphology with a thickness of 25 mu m. However, because of the presence of sulfate groups, thermal degradation and high redispersion in water occur, which affect the iridescent property of these biobased pigments. To overcome such limitations, two post-treatments are proposed. The sulfate ester groups are removed from the iridescent pigments with vacuum overdrying. The mass loss of iridescent pigment in water is reduced with an increase of the ionic strength in the aqueous medium by NaCl addition. These post-treatments have proven to be efficient and engineered pigments based on CNC films can be used to add anticounterfeiting features to packaging manufactured by classical paper techniques or extrusion. (C) 2015 Elsevier Ltd. All rights reserved.
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