期刊
INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
卷 219, 期 -, 页码 53-67出版社
ELSEVIER
DOI: 10.1016/j.ijbiomac.2022.07.239
关键词
Chitosan biopolymer; Metal-oxide nanoparticles; C-CS@ZnO; Methyl orange; Effluent treatment plant; Yoshida H-bonding
资金
- Department of Science and Technology (DST) , Government of India (GoI) [DST/INSPIRE Fellowship/2018/IF180719]
- Council of Scientific and Industrial Research (CSIR) , GoI [09/1343 (11547) /2021-EMR-I]
- Ministry of Europe and Foreign Affairs [mopga-postdoc-4-1619061645]
The textile/dyeing industries are known for their high water consumption and the resulting contamination of water bodies with dye-laden effluent. This study proposed a fast method for synthesizing a nanocomposite adsorbent (C-CS@ZnO) using microwave-assisted synthesis. The sorbent showed a high sorption capacity for methyl orange dye and demonstrated potential for large-scale textile effluent treatment. This research is significant for addressing the environmental impact of textile/dyeing industries.
Textile/Dyeing industries have been considered as one of the intense water-consuming units, resulting in the generation of a large volume of dye(s) contaminated effluent posing a heavy burden on the receiving water bodies. Therefore, the identification of methods to synthesize bulk quantity of adsorbent(s) and further their evaluation for the efficient treatment of effluent is one of the most prominent topics. Hence, microwave-assisted method was proposed for the rapid synthesis of nanocomposite (C-CS@ZnO) from natural biomolecule (chitosan-CS), a well-known crosslinker (tripolyphosphate) and metal-oxide (ZnO) nanoparticles. Detailed characterization was performed to identify the structure (SEM, XRD) and composition (FT-IR, XPS) of the sorbent. Sorption experiments with methyl orange (MO) dye solution were carried out under different pH (2.0-12.0), dye concentrations (150-350 mg L-1), reaction times (0-210 min) and temperature (25-45 degrees C) to establish the adsorbent at the lab-scale. The maximum sorption capacity (185.2 mg g(-1)) was obtained because of the ligand-exchange, Yoshida H-bonding and electrostatic interactions and was best elucidated by Freundlich (R-2 >= 0.99) and pseudo-second-order (R-2 >= 1) models. To simulate the field conditions, the effects of co-existing ions (anions/cations), cocktail dyes/ions mixture and regenerant were also studied. The obtained results suggest its promising applicability at a large scale for textile effluent treatment.
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