Regenerated cellulose/multiwalled carbon nanotube composite films with efficient electric heating performance

We have manufactured regenerated cellulose-based composite films reinforced with pristine multiwalled carbon nanotube (MWCNT) by a facile casting of cellulose/DMAc/LiCI solutions containing 0.2-10.0 wt% MWCNT and have investigated their application as electric heating materials by examining microstructure, thermal stability, and electrical properties. TEM images showed that the pristine MWCNT was dispersed well in the regenerated cellulose matrix. The composite films were found to be stable thermally up to similar to 275 degrees C. The electrical resistivity of the regenerated cellulose/MWCNT composite films decreased significantly from similar to 10(9) Omega cm to similar to 10(1) Omega cm with increasing the MWCNT loading, particularly at a certain MWCNT content between 2.0 and 3.0 wt%. Accordingly, the composite films with 5.0-10.0 wt% MWCNT contents, which possessed low electrical resistivity of similar to 10(2)-10(1) Omega cm, exhibited excellent electric heating performance in aspects of temperature responsiveness, steady-state maximum temperature, and electrical energy efficiency at constant applied voltages. For instance, the composite film with 10.0 wt% MWCNT had well-controlled steady-state maximum temperatures of 40-189 degrees C at 20-80V, characteristic temperature growth constant of similar to 1 s, and electric power efficiency of similar to 5.4 mW/degrees C, which performance remained unchanged under repeated experiments for several hours. (C) 2015 Elsevier Ltd. All rights reserved.