4.7 Review

Recent progress of rare earth conversion material in perovskite solar cells: A mini review

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Exploring low-temperature processed multifunctional HEPES-Au NSs-modified SnO2 for efficient planar perovskite solar cells

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Summary: Introducing HEPES-Au NSs into a SnO2 ETL can improve electronic properties and interface quality, leading to higher efficiency in perovskite solar cells. The chemical bond interaction and surface adsorption brought by HEPES-Au NSs play a crucial role in enhancing the performance of PSCs.

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Summary: Perovskite solar cells have shown great potential with reliable moisture and heat stability, but challenges remain in scaling up for large-area substrates. Strategies and materials are being developed for future commercial photovoltaic fabrications to overcome these challenges.

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Green antisolvent additive engineering to improve the performance of perovskite solar cells

Jiahui Li et al.

Summary: In this study, a green antisolvent of ethyl acetate (EA) with acetylacetone (AA) additive was used to fine-tune perovskite crystallization and passivate defects, resulting in the fabrication of uniform and compact CH3NH3PbI3 perovskite films with larger grains and fewer defect density. The power conversion efficiency (PCE) of the CH3NH3PbI3 PSCs was improved from 19.2% to 21.1% with enhanced stability in air by using this green antisolvent engineering strategy.

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Urea-complexed tin oxide as an electron transporting layer for stable and efficient planar perovskite solar cells

Zhou Liu et al.

Summary: SnO2 is attracting attention in planar perovskite solar cells due to its outstanding photoelectric properties and low temperature preparation. A simple method of ureacomplexed tin oxide in deionized water is effective in controlling SnO2 concentration and forming a compact surface morphology. The study also explored the impact of different thicknesses of SnO2 layers on PSC properties, with the 60 nm SnO2 layer showing the highest power conversion efficiency and fill factor.

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Feng Xu et al.

Summary: By synthesizing NaCsWO3@NaYF4@NaYF4:Yb,Er nanoparticles to enhance the UCL intensity, which were then used in PSCs, the power conversion efficiency of highly efficient PSCs reached 18.89%, showing a significant improvement compared to the control group.

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Enhanced photocurrent of perovskite solar cells by dual-sensitized β-NaYF4: Nd3+/Yb3+/Er3+ up-conversion nanoparticles

Mei Wang et al.

Summary: By using rare earth doped up-conversion nanoparticles with dual-sensitizers, the photocurrent density and power conversion efficiency of perovskite solar cells have been significantly increased.

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Excellent quinoline additive in perovskite toward to efficient and stable perovskite solar cells

Guodong Li et al.

Summary: The introduction of quinoline as an additive in perovskite material can improve the film quality and reduce defect density, leading to higher efficiency and stability of solar cells. By adjusting the amount of quinoline added, the photovoltaic performance of perovskite solar cells can be effectively enhanced.

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Intermediates transformation for efficient perovskite solar cells

Zhizai Li et al.

Summary: Perovskite materials have significantly improved in PCE, with intermediates transformation being a key factor in obtaining high-quality films, which can potentially enhance fabrication efficiency.

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Xiaojie Yang et al.

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Summary: Metal halide perovskite solar cells have shown great potential to disrupt the silicon solar cell market with their improved performance, yet still face limitations in light-harvesting due to charge carrier recombination. Efforts to enhance charge carrier management offer a path to increase device performance and approach the theoretical efficiency limit of PSCs.

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Carlos Pereyra et al.

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Cementitious grain-boundary passivation for flexible perovskite solar cells with superior environmental stability and mechanical robustness

Xiaotian Hu et al.

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Efficient and Stable Perovskite Solar Cells Using Bathocuproine Bilateral-Modified Perovskite Layers

Renjie Chen et al.

Summary: Surface modification engineering plays a crucial role in enhancing the crystallinity and passivating the interface and grain boundary of perovskite solar cells (PSCs), resulting in an improvement in power conversion efficiency (PCE) and stability. The introduction of n-type semiconductor bathocuproine (BCP) at the perovskite/transport layer interfaces showed significant enhancements in PCEs due to improved crystallinity and superior interface contact properties. Dual-sided BCP modification at both interfaces further improved crystallinity and contact properties, leading to higher PCEs and enhanced stability of the PSCs.

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Mechanism of bifunctional p-amino benzenesulfonic acid modified interface in perovskite solar cells

Yapeng Sun et al.

Summary: In this study, a dual-functional linking molecule ABSA is used to modify the interface between SnO2 ETL and perovskite layer, reducing energy band barrier, suppressing charge recombination, and passivating deep-level defects. This modification significantly improves the efficiency and stability of perovskite solar cells, providing a new perspective for interfacial engineering.

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Organic-inorganic upconversion nanoparticles hybrid in dye-sensitized solar cells

Anees A. Ansari et al.

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Steric effect of amino-acids as additives for perovskite solar cells

Haobo Yuan et al.

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Controlled growth of perovskite KMnF3 upconverting nanocrystals for near-infrared light-sensitive perovskite solar cells and photodetectors

Zhiying Feng et al.

Summary: A facile method using EDTAD-assisted hydrothermal approach was employed to grow rare-earth-element-doped KMnF3 nanocrystals with controllable size, which were proven to enhance the photovoltaic performance of PVSC devices. Proper molar ratio UCNCs as an additive facilitated the growth of semiconductor perovskite, resulting in improved crystallinity and compact grains in the perovskite film, ultimately leading to a significant improvement in mean power conversion efficiency (PCE) of PVSCs.

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Wide-bandgap organic-inorganic hybrid and all-inorganic perovskite solar cells and their application in all-perovskite tandem solar cells

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Mitigating ion migration in perovskite solar cells

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Muhammad Mujahid et al.

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