期刊
INORGANIC CHEMISTRY
卷 -, 期 -, 页码 -出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.2c02798
关键词
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资金
- National Natural Science Founda t i o n of China [22175175,21771179, 21901246]
- Fujian Science & Technology Innovation Laboratory for Optoelectronic Information of China [2021ZR118]
- Natural Science Foundation of Fujian Province [2019J01133]
- Youth Innovation Promotion Associ- ation CAS [2022303]
This study discovered two new types of one-dimensional chain-like oxychalcogenides with wide energy gaps and excellent UV-NLO performance, exhibiting comparable comprehensive properties to commercial materials.
Oxychalcogenides have gained widespread attention as promising infrared nonlinear optical (IR-NLO) candidates. However, high-performance oxychalcogenides have rarely been reported in the ultraviolet (UV) region owing to the low energy gaps (E-g < 4.0 eV). Herein, two non-centrosymmetric (NCS) oxychalcogenides with one-dimensional (1D) chain structures and wide E-g (>4.3 eV), namely, AEGeOS(2) (AE = Sr and Ba), have been discovered by combined experiments and theory calculations as a new source of UV-NLO materials. Significantly, they exhibit excellent comprehensive performance comparable to the commercial UV-NLO material KH2PO4 (KDP), including large phase-matching ranges (>380 nm), sufficient second harmonic generation intensities (0.7-1.1 X KDP), high laser-induced damage thresholds (1.2 X KDP), wide transparent regions (0.26-12.2 mu m), and good thermal stability (up to 1100 K). Moreover, systematic structure-activity relationship analysis illustrates that the 1D homochiral helical [GeOS2](2-) chains composed of heteroanionic [GeS2O2] units make major contribution to the desirable UV-NLO performance. This work makes the two compounds shine out as new energy in the UV-NLO field and offers a new perspective for the exploration of structure-driven functional oxychalcogenides.
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