期刊
INDUSTRIAL CROPS AND PRODUCTS
卷 188, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.indcrop.2022.115681
关键词
5-Hydroxymethylfurfural; Ternary solvent; Choline chloride; Glucose; Corn stover
资金
- Natural Science Foundation of Jiangsu Province [BK20181465]
- Postgraduate Research & Practice Innovation Program of Jiangsu Province [KYCX21-2862]
Aqueous choline chloride/acetone was developed as a green ternary solvent for catalytic conversion of glucose and raw corn stover into 5-HMF. The acidic choline chloride solution promoted the isomerization and dehydration of glucose to 5-HMF, while acetone acted as an efficient extracting solvent to remove 5-HMF from the aqueous phase. The composition of the ternary solvent system significantly affected the 5-HMF yield, reaction selectivity, and prevention of further degradation.
Aqueous choline chloride/acetone was developed as a green ternary solvent for catalytic conversion of glucose and raw corn stover into 5-HMF. The results illustrated that acidic ChCl solution played a vital role in promoting the tandem isomerization/dehydration reaction of glucose to 5-HMF, while acetone was identified as an efficient extracting solvent to simultaneously remove 5-HMF from the aqueous phase. The composition of the ternary solvent system was found to have a significant impact on the 5-HMF yield, reaction selectivity, and preventing the further degradation of 5-HMF. A competitive 5-HMF yield of 73.3 mol% was achieved from glucose catalyzed by an ultra-low H2SO4 loading of 2 mmol at 190 degrees C for 10 min in the ternary ChCl-H2O-acetone solvent with a mass ratio of 1:2:3. This novel solvent system exhibited good stability, high efficiency, and excellent recyclability, employing in catalytic conversion of both glucose and lignocellulose to produce 5-HMF.
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