4.7 Article

P-doped carbon as an efficient metal-free catalyst for alcoholysis of furfural alcohol to ethyl levulinate

期刊

FUEL
卷 324, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2022.124024

关键词

Furfural alcohol; Ethyl levulinate; Alcoholysis; Metal-free catalyst

向作者/读者索取更多资源

In this study, an economic and environmentally friendly carbon catalyst P-C-800 was developed for the synthesis of EL from FAL in a hot ethanol medium. The catalyst exhibited high catalytic activity and could be reused multiple times.
Ethyl levulinate (EL), as a potential fuel additive and versatile biomass-based platform molecule, has been the focus in the field of sustainable chemistry. In this contribution, a series of economic and environmental friendly biomass-derived P doped carbon catalysts were developed in this study for synthesis of EL from renewable furfural alcohol (FAL) in a hot ethanol medium. The carbon catalyst, P-C-800, synthesized via carbonizing the phytic acid at 800 ?C, exhibited a good catalytic activity in alcoholysis of FAL to EL. The highest yield of EL could be 79.7% with a complete conversion of FAL at 140 ?C in 6 h. Moreover, P-C-800 could be recovered efficiently and reused multiple times with sustained catalytic activity. It was revealed further by the detailed catalyst characterization and systematic evaluation of catalytic performance that both the acid content and surface area of the P-C-800 were crucial for the alcoholysis of FAL to EL.

作者

我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。

评论

主要评分

4.7
评分不足

次要评分

新颖性
-
重要性
-
科学严谨性
-
评价这篇论文

推荐

暂无数据
暂无数据