4.7 Article

Reaction site evolution during low-temperature oxidation of low-rank coal

期刊

FUEL
卷 327, 期 -, 页码 -

出版社

ELSEVIER SCI LTD
DOI: 10.1016/j.fuel.2022.125195

关键词

Low-temperature oxidation; Low-rank coal; Carbon type; Quantum chemistry; Reaction site

资金

  1. National Natural Science Foundation of China [51974308, 51974312]
  2. National key R&D Program of China [2019YFE0100100]
  3. Major Science and Technology Project of Shanxi Province [20181102017]

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In-depth and comprehensive analysis of reaction sites evolution during low-temperature oxidation provides important insights into the chemical reaction sequence. Through the combined use of FT-IR, XPS and C-13 NMR, changes in reaction sites were analyzed. The results show that as the oxidation temperature increases, the reactivity of methylene increases and the ratio of CH3/CH2 also increases. Before the temperature reaches 150 degrees C, the content of C-H slightly decreases while that of C-O increases. Subsequently, C-O gradually transforms into C=O. When the oxidation temperature exceeds 150 degrees C, the ratio of aliphatic carbon decreases significantly, while that of aromatic carbon and carbonyl carbon increase. The study identifies hydroxyl, methyl and methylene groups, especially the hydroxyl in the carboxyl group, as the main active site for coal oxidation at low temperatures.
In-depth and comprehensive analysis of reaction sites evolution has important enlightening significance for understanding the chemical reaction sequence during low-temperature oxidation. For this purpose, FT-IR, XPS and C-13 NMR were combined to analyze the changes in reaction sites. As the oxidation temperature increased, the CH3/CH2 ratio continuously increases, indicating that methylene has a higher reactivity. Before the oxidation temperature reached 150 degrees C, the relative content of C-H decreased slightly while that of C-O increased. Then, the C-O gradually transformed into C=O. When the oxidation temperature exceeds 150 degrees C, the ratio of aliphatic carbon has been significantly reduced and that of aromatic carbon is greatly increased. The ratio of carbonyl carbon also has a small increase. Based on these results, representative macromolecular models are established and electrostatic potential analysis is performed. The results show that the main active site is the hydroxyl, methyl and methylene groups, especially the hydroxyl in the carboxyl group. In summary, it can be considered that the main active sites for coal oxidation at low temperature are hydroxyl and methylene groups. At higher temperatures, the hydroxyl group will be further oxidized and the main active site will gradually evolve into carboxyl groups.

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